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  • 708763 - [(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

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708763 Aldrich

[(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

Synonym: [PdCl2{(S)-4-tolylbinap}]

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Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   ADMKISPNGKUJAU-UHFFFAOYSA-L
mp   >300 °C

Description

Packaging

100, 500 mg in glass insert

Application

Catalyst for:
• Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidation
• Asymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

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Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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