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71290 Aldrich

Sodium azide

purum p.a., ≥99.0% (T)

Synonym: Hydrazoic acid sodium salt, NSC 3072

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Properties

Related Categories Azidation/Diazo Transfer, C-X Bond Formation (Non-Halogen), Chemical Synthesis, Synthetic Reagents
InChI Key   PXIPVTKHYLBLMZ-UHFFFAOYSA-N
grade   purum p.a.
assay   ≥99.0% (T)
solubility   H2O: soluble0.1 g/mL, clear, colorless
anion traces   chloride (Cl-): ≤50 mg/kg
  sulfate (SO42-): ≤50 mg/kg
cation traces   Ca: ≤50 mg/kg
  Cd: ≤50 mg/kg
  Co: ≤50 mg/kg
  Cu: ≤50 mg/kg
  Fe: ≤50 mg/kg
  K: ≤100 mg/kg
  Ni: ≤50 mg/kg
  Pb: ≤50 mg/kg
  Zn: ≤50 mg/kg

Description

Other Notes

Schmidt reaction with aldehydes and carboxylic acids, a review

Application

Catalyst for:
• Oxidative decarboxylation
• Michael addition reactions

Reagent for synthesis of
• Blue fluorescent copolymers
• Metal phosphonates
• Arenes via aminations

Involved in regioselective synthesis of prianosin B

Price and Availability


Laboratory Gloves
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Brain
Supplemental Hazard Statements 
Contact with acids liberates very toxic gas.
RIDADR 
UN 1687 6.1 / PGII
WGK Germany 
2
RTECS 
VY8050000
Protocols & Articles
Peer-Reviewed Papers
15

References

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