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723002 Aldrich

Cyanomethyl methyl(phenyl)carbamodithioate

98% (HPLC)

Synonym: Cyanomethyl N-methyl-N-phenyl dithiocarbamate

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Properties

Related Categories Dithiocarbamates, Materials Science, Polymer Science, RAFT Agents, Reagents for Controlled Radical Polymerization,
InChI Key   FYACMHCOSCVNHO-UHFFFAOYSA-N
assay   98% (HPLC)
form   powder
mol wt   average Mn 8,000
mp   88-92 °C
storage temp.   2-8°C

Description

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of vinyl ester and vinyl amide monomers. Chain Transfer Agent (CTA)

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Packaging

1, 5 g in glass bottle

Legal Information

Sold for research purposes only: See sigma-aldrich.com/raftlicense. Patents: WO98/01478; WO99/311444.

Protocols & Applications

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteri...
Keywords: Biomaterials, Living polymerization, Nanotechnology, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, transformation

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents

Concepts and Tools for RAFT Polymerization

RAFT or Reversible Addition/Fragmentation Chain Transfer is a form of living radical polymerization. RAFT polymerization was discovered at CSIRO in 1998.1 It soon became the focus of intensive resear...
Keywords: Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Hua Wei1 and Suzie H. Pun2* 1Department of Chemistry, Lanzhou University, Lanzhou 730000 China 2Department of Bioengineering and Molecular Engineering and Sciences Institute University of Washington,...
Keywords: Aminolysis, Asymmetric synthesis, Bacterial conjugations, Biomaterials, Catalysis, Click chemistry, Cycloadditions, Degradations, Growth factors, Immobilization, Living polymerization, PAGE, Peptide synthesis, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Ring-opening polymerization, Solid phase peptide synthesis, Transfection, transformation

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteri...
Graeme Moad, Ezio Rizzardo, and San H. Thang
Material Matters 2010, 5.1, 2.
Keywords: Applications, Biomaterials, Living polymerization, Methods, Nanotechnology, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, Support, Type, transformation

Select RAFT Agents for Making Well-Defined Functionalized Polymers

The supply of low cost, high purity and effective Reversible addition−fragmentation chain-transfer (RAFT) Agents is the essential element in the industrial implementation of RAFT polymerization techn...
Liz G. Williamsa, Ken Sullivanb and John Tsanaktsidisa

a CSIRO Manufacturing, Ian Wark Laboratory, Bayview Avenue, Clayton, Victoria 3168, Australia, and
b Boron Molecular INC, 2650-110 Discovery Drive, Raleigh, NC 27616 USA
Keywords: Polymerization reactions, Reversible addition-fragmentation chain transfer polymerizations

Tools for Performing ATRP (Atom Transfer Radical Polymerization)

Controlled radical polymerization (CRP) techniques have been reviewed in a number of articles1,2 and books,3 and include nitroxide-mediated polymerization (NMP),4-7 reversible addition fragmentation ...
Keywords: Ligands, Materials Science, Polymerization reactions, Purification, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization

Typical Procedures for Polymerizing via ATRP

The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents

Typical Procedures for Polymerizing via RAFT

RAFT (Reversible Addition/Fragmentation Chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a sui...
Keywords: Nuclear magnetic resonance spectroscopy, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Protocols

RAFT Polymerization Procedure

RAFT (Reversible Addition-Fragmentation chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a sui...
Keywords: Nuclear magnetic resonance spectroscopy, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Related Content

RAFT Evaluation

In 1998, members of an Australian Commonwealth Scientific and Research Organization (CSIRO) team discovered the RAFT polymerization method.1
Keywords: Cell biology, Electronics, Materials Science, Polymerization reactions, Reversible addition-fragmentation chain transfer polymerizations, Solvents

RAFT Polymerization Lecture Video - Materials Science

Dr. Ezio Rizzardo, Chief Scientist at the Commonwealth Scientific and Industrial Research Organization (CSIRO), presents an overview of Reversible Addition Fragmentation Chain Transfer (RAFT) Polymer...
Keywords: Deprotonations, Materials Science, Polymerization reactions, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations

Peer-Reviewed Papers
15

References

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