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777692 Aldrich

(1,10-Phenanthroline)(trifluoromethyl)copper(I)

90%

Synonym: Trifluoromethylator®

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Properties

Related Categories Chemical Synthesis, Fluorination Reagents, Synthetic Reagents, Trifluoromethylation
InChI Key   CUQZQRIIFNWQSJ-UHFFFAOYSA-N
assay   90%
storage temp.   2-8°C

Description

Packaging

1, 10, 100 g in glass bottle

500 mg in glass insert

Application

Trifluoromethylator, A New Arene Trifluoromethylation Reagent: (Phen)Cu-CF3

(Phen)Cu-CF3 is an easily handled, thermally stable, single-component reagent for the trifluoromethylation of aryl iodides. Electron-rich and electron-deficient iodoarenes, as well as sterically-hindered iodoarenes, react in high yield under mild conditions. Electrophilic functional groups, including aldehydes, nitroarenes, ketones and esters are tolerated. The substrate scope of this reagent is broad and the reagent has wide applicability for trifluoromethylation reactions.

Legal Information

Trifluoromethylator is a registered trademark of Catylix, Inc

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Baran Reagents FAQs

What do the Baran reagents do? Allow the placement of alkyl groups onto molecules in drug discovery by replacing a C-H bond with the corresponding C-C bond (trifluoromethyl, difluoromethyl, isopropyl...
Keywords: Agrochemicals, Alkylations, Drug discovery, Fluorinations, Liquid chromatography mass spectrometry, Medicinal chemistry, Nuclear magnetic resonance spectroscopy, PAGE, Solvents

Hartwig Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Hartwig Group – Professor Product Portal
Keywords: Aminations, Asymmetric synthesis, Catalysis, Cross couplings, Fluorinations, Hydroaminations, Infrared spectroscopy, Ligands, Oxidations, Silylations, Suzuki reactions

Peer-Reviewed Papers
15

References

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