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78175 Aldrich

N-Phenyl-bis(trifluoromethanesulfonimide)

≥98.0% (HPLC)

Synonym: 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, NSC 240874, Phenyl triflimide

  • CAS Number 37595-74-7

  • Linear Formula C6H5N(SO2CF3)2

  • Molecular Weight 357.25

  •  Beilstein Registry Number 1269141

  •  MDL number MFCD00000404

  •  PubChem Substance ID 24887270

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Properties

Related Categories Chemical Synthesis, Coupling, Synthetic Reagents, Triflate Formation
InChI Key   DIOHEXPTUTVCNX-UHFFFAOYSA-N
assay   ≥98.0% (HPLC)
mp   100-102 °C(lit.)
  100-102 °C

Description

Other Notes

Stable, crystalline and easy-to-handle triflating agent, useful for the triflation of phenols and amines (especially aliphatic secondary amines; aromatic secondary amines do not react); For the preparation of triflones; For the preparation of enol triflates from ketones

Packaging

5, 25, 50 g in glass bottle

Application

Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes

Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
Peer-Reviewed Papers
15

References

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