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857319 Aldrich

Chloramine-T hydrate

95%

Synonym: N-Chloro-p-toluenesulfonamide sodium salt hydrate

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Description

Application

A review.2

Capable of oxidative cyclization to produce various heterocycles.

Nitrene source for aziridinations and aminohydroxylations.

Reactant for:
• Preparation of factor Xa inhibitors as novel anticoagulants1

Packaging

1 kg in poly bottle

100 g in poly bottle

5 g in glass bottle

Price and Availability

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Chloramine T trihydrate

ACS reagent, 98%

Chloramine T trihydrate

purum p.a., for the detection of halogens and bromate, ≥98.0% (RT)

Chloramine T trihydrate

puriss. p.a., Reag. Ph. Eur., ≥99%

Chloramine T trihydrate

meets analytical specification of Ph. Eur., BP, 98-103%

<I>N</I>-<WBR>Chlorobenzenesulfonamide sodium salt

~28% active chlorine basis

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Contact with acids liberates toxic gas.
RIDADR 
UN 3263 8 / PGIII
WGK Germany 
2

Protocols & Articles

Peer-Reviewed Papers

References

Set your institution to view full text papers.

1. Structure-based design of novel guanidine/benzamidine mimics: potent and orally bioavailable factor Xa inhibitors as novel anticoagulants. Lam, P. Y. S.; et al. J. Med. Chem. 46, 4405, (2003)

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2. J. Sci. Ind. Res. 49, 13, (1990)

Silica-water reaction media: its application to the formation and ring opening of aziridines. Minakata, S. et al Angew. Chem. Int. Ed. Engl. 43, 79, (2004)

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Mogilaiah, K.; Reddy, G. R. J. Chem. Res. (M), 145, (2004)

Pal, A. et al Tetrahedron 55, 4123, (1999)

Kantam, M. L. et al Tetrahedron Lett. 44, 9029, (2003)

Kano, D. et al J. Chem. Soc. Perkin Trans. I, 3186, (2001)

Brandt, P. et al J. Am. Chem. Soc. 122, 8013-8020, (2000)

Jeong, J. U. et al J. Am. Chem. Soc. 120, 6844, (1998)

Rudolph, J. et al Angew. Chem. Int. Ed. Engl. 35, 2810, (1996)

Li, G. et al Angew. Chem. Int. Ed. Engl. 35, 451, (1996)

Catalytic asymmetric aminohydroxylation provides a short taxol side-chain synthesis. Li, G.; Sharpless, K. B. Acta Chem. Scand. 50, 649, (1996)

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Heteropoly acid as a novel nitrene transfer agent: a facile and practical aziridination of olefins with Chloramine-T. Kumar, G. D. K.; Baskaran, S. Chem. Commun. (Camb.), 1026, (2004)

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Fieser 4,445 / Fieser 5,104 / Fieser 7,58 / Fieser 8,83 / Fieser 9,101 / Fieser 10,85 / Fieser 11,118 / Fieser 13,70 / Fieser 15,78

Aldrich MSDS 1, 364:C / Corp MSDS 1 (1), 722:B / FT-IR 1 (2), 530:D / FT-IR 2 (2), 3289:C / FT-NMR 1 (2), 1631:C / IR-Spectra (3), 1175:C / IR-Spectra (2), 1023:G / NMR-Reference 2 (2), 849:C / Sax 6, 668 / Sigma FT-IR 1 (2), 368:C / Structure Index 1, 351:D:5

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