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92750 Aldrich

Dimethyl trimethylsilylmethylphosphonate

≥97.0%

Synonym: [(Trimethylsilyl)methyl]-phosphonic acid dimethyl ester

  • CAS Number 13433-42-6

  • Linear Formula (CH3)3SiCH2P(O)(OCH3)2

  • Molecular Weight 196.26

  •  Beilstein Registry Number 2412153

  •  MDL number MFCD00042921

  •  PubChem Substance ID 57653489

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents More...
InChI Key   QBHFBIHXALNDCB-UHFFFAOYSA-N
assay   ≥97.0%
refractive index   n20/D 1.435(lit.)
  n20/D 1.435
bp   111-114 °C/21.5 mmHg(lit.)
density   1.024 g/mL at 25 °C(lit.)

Description

Other Notes

Reagent for the preparation of olefinic sugar phosphonates; For the direct methylenation of carbonyl compounds

Application

Reactant for:
• Synthesis of phosphonato-phosphine palladacycles
• Studying the synthetic applications of phosphoryl-stabilized anions
• Peterson olefination reactions
• Dilithiation and transmetalation

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
159.8 °F
Flash Point(C) 
71 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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