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MilliporeSigma

A88107

p-Anisaldehyde

98%

Synonym(s):

p-Methoxybenzaldehyde, 4-Methoxybenzaldehyde, Aubépine

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5 G

$40.10

100 G

$53.50

500 G

$102.00

1 KG

$155.00

$40.10


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About This Item

Linear Formula:
CH3OC6H4CHO
CAS Number:
Molecular Weight:
136.15
Beilstein/REAXYS Number:
471382
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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vapor density

4.7 (vs air)

Quality Level

assay

98%

form

liquid

refractive index

n20/D 1.573 (lit.)

bp

248 °C (lit.)

mp

−1 °C (lit.)

density

1.119 g/mL at 25 °C (lit.)

SMILES string

[H]C(=O)c1ccc(OC)cc1

InChI

1S/C8H8O2/c1-10-8-4-2-7(6-9)3-5-8/h2-6H,1H3

InChI key

ZRSNZINYAWTAHE-UHFFFAOYSA-N

Gene Information

human ... CYP1A2(1544)

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This Item
W267007W267020129488
assay

98%

assay

≥97.5%

assay

-

assay

97%

Quality Level

200

Quality Level

400

Quality Level

400

Quality Level

100

density

1.119 g/mL at 25 °C (lit.)

density

1.119 g/mL at 25 °C (lit.)

density

1.119 g/mL at 25 °C (lit.)

density

-

form

liquid

form

liquid

form

liquid

form

powder

refractive index

n20/D 1.573 (lit.)

refractive index

n20/D 1.573 (lit.)

refractive index

n20/D 1.573 (lit.)

refractive index

-

bp

248 °C (lit.)

bp

248 °C (lit.)

bp

248 °C (lit.)

bp

-

Application

p-Anisaldehyde may be used as a triplet sensitizer to catalyze the photochemical intermolecular atom-transfer radical addition (ATRA) of haloalkanes onto olefins.[1] It can be used to synthesize 2-(4-methoxybenzylidene)-N-(4-(N-(1-phenyl-1H-pyrazol-5-yl)sulfamoyl)phenyl) hydrazinecarbothioamide.[2] It is also used as a stain for detecting non UV-active substances using thin layer chromatography (TLC).[3]

pictograms

Health hazard

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - Repr. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

240.8 °F - closed cup

flash_point_c

116 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Synthesis, structural characterization and anticancer evaluation of pyrazole derivatives.
El-Gaby MS
Medicinal Chemistry Research, 27(1), 72-79 (2018)
Photo?Organocatalysis of Atom?Transfer Radical Additions to Alkenes.
Arceo E
Angewandte Chemie (International Edition in English), 53(45), 12064-12068 (2014)
Qingyao Wu et al.
Nature communications, 12(1), 483-483 (2021-01-22)
Artificial photosynthesis of H2O2 from H2O and O2, as a spotless method, has aroused widespread interest. Up to date, most photocatalysts still suffer from serious salt-deactivated effects with huge consumption of photogenerated charges, which severely limit their wide application. Herein
Stereocontrolled cascade cyclisation of campholenic enol?ether derivatives: en route to vetiver?scented spiroxides.
Ondet P
European Journal of Organic Chemistry, (8), 980-989 (2018)
Guozhu Zhang et al.
Journal of the American Chemical Society, 130(38), 12598-12599 (2008-08-30)
A novel approach to generate Au-containing all-carbon 1,3-dipoles is developed via an unprecedented migration-fragmentation of ketals/acetals. These in situ generated dipoles undergo rapid [3+2] cycloaddition under mild conditions with various enones/enals, electron-rich aromatic aldehydes, and N-benzylindole, leading to flexible formation

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Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Is there any literature reference regarding its properties?

    1 answer
    1. There are many properties available for p-Anisaldehyde. These are listed in the PROPERTIES section of the product listing. Publications associated with this product can be reviewed at the link below: https://www.sigmaaldrich.com/search/a88107?focus=papers&page=1&perpage=30&sort=relevance&term=a88107&type=citation_search There are a number of p-Anisaldehyde are currently available, in addition to the A88107. A list of these products can be reviewed below: https://www.sigmaaldrich.com/substance/panisaldehyde13615123115 Product SRA1 Anisaldehyde solution, is intended for use in detection of a number of compounds. There is additional information, as well as a number of references cited, in the product datasheet. Please see the link below to review: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/product/documents/106/699/sra1dat.pdf

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