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A88255 Aldrich

p-Anisidine

≥99%

Synonym: 4-Aminoanisole, 4-Methoxyaniline

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Properties

Related Categories Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds,
assay   ≥99%
autoignition temp.   959 °F
bp   240-243 °C(lit.)
mp   56-59 °C(lit.)

Description

Packaging

1 kg in glass bottle

5, 100, 250 g in glass bottle

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
Flash Point(F) 
251.6 °F
Flash Point(C) 
122 °C

Protocols & Articles

Articles

Determination of Water Content in 4-Anisidine Using Karl Fischer Titration

Nitrogen compounds, acid amides and weakly basic amines (heterocyclenes) give no problems. They can be titrated according to the standard procedures. Strongly basic amines alter the pH value and must...
Keywords: Titrations

Peer-Reviewed Papers

References

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Direct asymmetric three-component organocatalytic anti-selective Mannich reactions in a purely aqueous system. Cheng L, Wu X, and Lu Y Org. Biomol. Chem. 5(7), 1018-20, (2007)

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[Toxicological and hygienic characteristics of ortho- and para-anisidines]. Ilichkina AG Gig. Sanit. (6), 77-8, (1985)

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[Determination of seven aromatic amines in hair dyes by capillary electrophoresis coupled with field-amplified sample stacking]. Lu Y, Wang H, Song P, et al. Se Pu 29(11), 1122-7, (2011)

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[One case of acute 4-methoxyaniline poisoning in a transportation worker]. Zhang JL, Zhou WJ, and Qin H Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi 25(12), 717, (2007)

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Sensitivity "hot spots" in the direct analysis in real time mass spectrometry of nerve agent simulants. Harris GA, Falcone CE, and Fernández FM J. Am. Soc. Mass Spectrom. 23(1), 153-61, (2012)

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Concise synthesis of (+/-)-horsfiline and (+/-)-coerulescine by tandem cyclisation of iodoaryl alkenyl azides. Lizos DE and Murphy JA Org. Biomol. Chem. 1(1), 117-22, (2003)

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Effect of storage on chemical and sensory profiles of peanut pastes prepared with high-oleic and normal peanuts. Riveros CG, Mestrallet MG, Gayol MF, et al. J. Sci. Food Agric. 90(15), 2694-9, (2010)

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Synthesis and evaluation of changes induced by solvent and substituent in electronic absorption spectra of some azo disperse dyes. Mohammadi A, Yazdanbakhsh MR, and Farahnak L Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 89, 238-42, (2012)

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Enantioselective aminolysis of an alpha-chloroester catalyzed by Candida cylindracea lipase encapsulated in sol-gel silica glass. Badjić JD, Kadnikova EN, and Kostić NM Org. Lett. 3(13), 2025-8, (2001)

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L-proline-catalyzed enantioselective one-pot cross-Mannich reaction of aldehydes. Hayashi Y, Urushima T, Tsuboi W, et al. Nat. Protoc. 2(1), 113-8, (2007)

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Comparing antioxidant effectiveness of natural and synthetic free radical scavengers in thermally-oxidized lard using DPPH method. Yeo JD, Jeong MK, Park CU, et al. J. Food Sci. 75(3), C258-62, (2010)

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Esterified propoxylated glycerol soyate, a fat substitute model compound, and soy oil after heating. Artz WE, Soheili KC, and Arjona IM J. Agric. Food Chem. 47(9), 3816-21, (1999)

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cDNA microarray gene expression profiling of hydroxyurea, paclitaxel, and p-anisidine, genotoxic compounds with differing tumorigenicity results. Lee M, Kwon J, Kim SN, et al. Environ. Mol. Mutagen. 42(2), 91-7, (2003)

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Aryl H-phosphonates 17: (N-aryl)phosphoramidates of pyrimidine nucleoside analogues and their synthesis, selected properties, and anti-HIV activity. Joanna Romanowska et al J. Med. Chem. 54, 6482-91, (2011)

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The modification of guanine nucleosides and nucleotides by the borderline arylamine carcinogens 4-methyl- and 4-methoxyaniline: chemistry and structural characterization. Meier C and Boche G Carcinogenesis 12(9), 1633-40, (1991)

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Synthetically functionalized retroviruses produced from the bioorthogonally engineered cell surface. Wong S and Kwon YJ Bioconjug. Chem. 22(2), 151-5, (2011)

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The results of five coded compounds: genistein, metaproterenol, rotenone, p-anisidine and resorcinol tested in the pH 6.7 Syrian hamster embryo cell morphological transformation assay. Harvey JS, Howe JR, Lynch AM, et al. Mutagenesis 20(1), 51-6, (2005)

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Mechanism of peptide hydrolysis by co-catalytic metal centers containing leucine aminopeptidase enzyme: a DFT approach. Zhu X, Barman A, Ozbil M, et al. J. Biol. Inorg. Chem. 17(2), 209-22, (2012)

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Principal component analysis of measured quantities during degradation of hydroperoxides in oxidized vegetable oils. Héberger K, Keszler A, and Gude M Lipids 34(1), 83-92, (1999)

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An efficient and convenient synthesis of ethyl 1-(4-methoxyphenyl)-5-phenyl-1H-1,2,3-triazole-4-carboxylate. Chen JH, Liu SR, and Chen K Chem. Asian J. 5(2), 328-33, (2010)

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Differential patterns of constitutive intracellular laccases of the vegetative phase of Pleurotus species. Téllez-Téllez M, Sánchez C, Loera O, et al. Biotechnol. Lett. 27(18), 1391-4, (2005)

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Influence of processing and storage time on the lipidic fraction of taralli. Caponio F, Summo C, Pasqualone A, et al. J. Food Sci. 74(9), C701-6, (2009)

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Structure-activity relationships of several anisidine and dibenzanthracene isomers in the w/w+ somatic assay of Drosophila melanogaster. Rodriguez-Arnaiz R and Téllez GO Mutat. Res. 514(1-2), 193-200, (2002)

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Quality assessment of palm products upon prolonged heat treatment. Tarmizi AH and Lin SW J. Oleo Sci. 57(12), 639-48, (2008)

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Small-molecule aggregation inhibitors reduce excess amyloid in a trisomy 16 mouse cortical cell line. Paula Lima AC, Arriagada C, Toro R, et al. Biol. Res. 41(2), 129-36, (2008)

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4-Methoxyanilinium tetrafluoroborate-dibenzo-18-crown-6 (1/1). Fu XQ, Yang YL, and Ye Q Acta Crystallogr. C 66(Pt 8), o433-5, (2010)

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Beil. 13,IV,1015

Aldrich MSDS 1, 128:D / Corp MSDS 1 (1), 276:A / IR-Spectra (2), 638:G / IR-Spectra (3), 724:E / NMR-Reference 2 (1), 1013:B / RegBook 1 (1), 1397:H / Sax 6, 284 / Sigma FT-IR 1 (2), 287:C / Structure Index 1, 217:B:2 / Vapor Phase 3, 1127:D

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