EMAIL THIS PAGE TO A FRIEND
ALD00386 Aldrich

Fe(dibm)3

Synonym: Baran Olefin Cross-Coupling Catalyst, Iron tris(diisobutyrylmethane)

  • CAS Number 24444-72-2

  • Empirical Formula (Hill Notation) C27H45FeO6

  • Molecular Weight 521.49

  •  PubChem Substance ID 329772664

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Non-Precious Metal Catalysis
InChI Key   LKNJSJQVZKKQHU-UHFFFAOYSA-N
mp   96-102 °C

Description

Packaging

100 mg in glass bottle

Application

Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions.

Other Notes

The Baran Laboratory Blog: Functionalized Olefin Cross-Coupling

Functionalized olefin cross-coupling to construct carbon–carbon bonds

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles

Articles

Baran Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Baran Group - Professor Product Portal
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?