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B57702 Aldrich

Bromobenzene

ReagentPlus®, 99%

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Properties

Related Categories Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons,
grade   ReagentPlus®
vapor density   5.41 (vs air)
vapor pressure   10 mmHg ( 40 °C)
InChI Key   QARVLSVVCXYDNA-UHFFFAOYSA-N
assay   99%
autoignition temp.   1051 °F
expl. lim.   36.5 %
refractive index   n20/D 1.559(lit.)
bp   156 °C(lit.)
mp   −31 °C(lit.)
density   1.474 g/mL at 25 °C
  1.491 g/mL at 25 °C(lit.)

Description

Packaging

100, 500 mL in glass bottle

18 L in steel drum

2 L in glass bottle

Application

Bromobenzene was used in the synthesis of four-armed star chain transfer agent, required for the preparation of amphiphilic star graft copolymers. It was employed as organic extraction phase in the Ion pair-based dispersive liquid-liquid microextraction of ultratrace levels of gold in water samples, soils and river sediments.

General description

Bromobenzene is an aryl chloride. It participates in the optimized palladium/metal oxide systems catalyzed Heck reactions of the non-activated and deactivated aryl chlorides. Heck reaction of bromobenzene with styrene using palladacycle as catalyst has been reported. It induces hepatic necrosis, via the formation of a reactive metabolite.

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 2514 3 / PGIII
WGK Germany 
2
Flash Point(F) 
123.8 °F
Flash Point(C) 
51 °C
Protocols & Articles

Articles

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes, and aryl or vinyl halides (or triflates) to afford substituted alkenes.1,2 It is a useful carbon–carbon bond form...
Keywords: Asymmetric synthesis, Cancer, Catalysis, Coupling reactions, Cross couplings, Heck Reaction, Herbicides, Ligands, Organic synthesis, Solvents

Peer-Reviewed Papers
15

References

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