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B75956 Aldrich

4-Bromophenylboronic acid

≥95.0%

Synonym: (p-Bromophenyl)boronic acid, 4-Bromobenzeneboronic acid, 4-Bromophenylboric acid, p-Bromobenzeneboronic acid, p-Bromophenylboric acid, NSC 25407

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Description

Other Notes

Contains varying amounts of anhydride

Packaging

5 g in glass bottle

Application

Reagent used for
• Palladium catalyzed Suzuki-Miyaura cross-couplings
• Pd(II)-catalyzed diastereoselective conjugate additions
• Palladium-catalyzed stereoselective Heck-type reaction of allylic esters with arylboronic acids
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides
• Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes
• Copper-catalyzed cross-couplings

Reagent used in Preparation of
• Gallate-based obovatol analogs with potential anti-tumor activity
• Protein modulators and enzymatic and kinase inhibitors

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
WGK Germany 
3
RTECS 
CY8650000
Protocols & Articles

Articles

Arylboronic Acids

Aldrich is pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give ...
Aldrich ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

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