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C71203 Aldrich

4-Chlorostyrene

97%, contains 500 ppm 4-tert-butylcatechol as inhibitor

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Properties

Related Categories Materials Science, Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers
vapor pressure   0.68 mmHg ( 20 °C)
InChI Key   KTZVZZJJVJQZHV-UHFFFAOYSA-N
assay   97%
contains   500 ppm 4-tert-butylcatechol as inhibitor
refractive index   n20/D 1.565(lit.)
bp   192 °C(lit.)
density   1.155 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

10, 50 g in glass bottle

Application

4-Chlorostyrene was used in the following studies:
• Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
• Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
• To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

General description

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).

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Safety & Documentation

Safety Information

RIDADR 
NA 1993 / PGIII
WGK Germany 
3
Flash Point(F) 
154.4 °F
Flash Point(C) 
68 °C
Protocols & Articles

Articles

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes, and aryl or vinyl halides (or triflates) to afford substituted alkenes.1,2 It is a useful carbon–carbon bond form...
Keywords: Asymmetric synthesis, Cancer, Catalysis, Coupling reactions, Cross couplings, Heck Reaction, Herbicides, Ligands, Organic synthesis, Solvents

Peer-Reviewed Papers
15

References

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08168 Timestrip Plus 8 °C

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