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E14403 Aldrich

Ethyl α-bromoisobutyrate

98%

Synonym: Ethyl 2-bromo-2-methylpropionate

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Properties

Related Categories ATRP, ATRP Initiators, Building Blocks, C6 to C7, Carbonyl Compounds,
InChI Key   IOLQWGVDEFWYNP-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.444(lit.)
bp   65-67 °C/11 mmHg(lit.)
density   1.329 g/mL at 25 °C(lit.)

Description

Application

Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with an ethyl end group.

Packaging

5, 100, 500 g in glass bottle

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
140 °F
Flash Point(C) 
60 °C
Protocols & Articles

Articles

ATRP Polymerization

Atom transfer radical polymerization (ATRP) provides a simple route to many well-defined (co)polymers with predetermined molecular weight, narrow molecular weight distribution, and high degree of cha...
Wojciech Jakubowski, Nicolay V. Tsarevsky and Patrick McCarthy
ATRP Solutions, Inc., 166 N. Dithridge Street, Suite G4, Pittsburgh, PA 15213
Keywords: Click chemistry, Gas chromatography, Hydrosilylations, Ligands, Nuclear magnetic resonance spectroscopy, Nucleophilic substitutions, Oxidations, Polymerization reactions, Precipitation, Purification, Radical polymerization, Size-exclusion chromatography, Substitutions

ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers

Atom transfer radical polymerization (ATRP)1-4 has emerged as one of the most successful synthetic techniques for the preparation of polymers with predetermined molecular weights, narrow molecular we...
Wojciech Jakubowski, Nicolay V. Tsarevsky, Patrick McCarthy
Material Matters 2010, 5.1, 16.
Keywords: Applications, Articles, Catalysis, Detergents, Gas chromatography, Hydrosilylations, Ligands, Methods, Nanotubes, Nuclear magnetic resonance spectroscopy, Nucleophilic substitutions, Oxidations, Polymerization reactions, Precipitation, Purification, Radical polymerization, Size-exclusion chromatography, Solvents, Substitutions, Type

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents

Typical Procedures for Polymerizing via ATRP

The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents

Related Content

ATRP Polymerization

Atom transfer radical polymerization (ATRP) provides a simple route to many well-defined (co)polymers with predetermined molecular weight, narrow molecular weight distribution, and high degree of cha...
Keywords: Click chemistry, Gas chromatography, Hydrosilylations, Ligands, Nuclear magnetic resonance spectroscopy, Nucleophilic substitutions, Oxidations, Polymerization reactions, Precipitation, Purification, Radical polymerization, Size-exclusion chromatography, Substitutions

Peer-Reviewed Papers
15

References

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