ARGET ATRP: Procedure for PMMA Polymer Brush Growth
Surface preparation before polymer brush growth consists of two steps: surface cleaning and initiator monolayer deposition.
Keywords: Deposition, Nucleic acid annealing, Polymerization reactions, Solvents
ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers
Atom transfer radical polymerization (ATRP)1-4 has emerged as one of the most successful synthetic techniques for the preparation of polymers with predetermined molecular weights, narrow molecular we...
Wojciech Jakubowski, Nicolay V. Tsarevsky, Patrick McCarthy
Material Matters 2010, 5.1, 16.
Keywords: Catalysis, Detergents, Gas chromatography, Hydrosilylations, Ligands, Nanotubes, Nuclear magnetic resonance spectroscopy, Nucleophilic substitutions, Oxidations, Polymerization reactions, Precipitation, Purification, Radical polymerization, Size-exclusion chromatography, Solvents, Substitutions
Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization
In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents
Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands
Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents
Typical Procedures for Polymerizing via ATRP
The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents
ATRP Polymerization
Atom transfer radical polymerization (ATRP) provides a simple route to many well-defined (co)polymers with predetermined molecular weight, narrow molecular weight distribution, and high degree of cha...
Keywords: Click chemistry, Gas chromatography, Hydrosilylations, Ligands, Nuclear magnetic resonance spectroscopy, Nucleophilic substitutions, Oxidations, Polymerization reactions, Precipitation, Purification, Radical polymerization, Size-exclusion chromatography, Substitutions
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