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E35702 Aldrich

Ethyl 4-methyl-2-cyclohexanone-1-carboxylate

Synonym: 4-Methyl-2-oxocyclohexanecarboxylic acid ethyl ester, Ethyl 4-methyl-2-oxo-1-cyclohexanecarboxylate, NSC 84213

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Properties

Related Categories Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   FFVHHWOJYFCNJP-UHFFFAOYSA-N
impurities   10% methyl ester
refractive index   n20/D 1.473(lit.)
bp   128-132 °C/32 mmHg(lit.)
density   1.045 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

Reactant involved in:
• Hydroxylation / oxidative chlorination with hydrogen peroxide
• Heterocyclization
• Cyclization of generated dianions followed by dehydrogenation
• Palladium-catalyzed isomerization
• Regioselective cyclizations
• Vinylogous Michael reactions

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Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>235.4 °F
Flash Point(C) 
>113 °C
Protocols & Articles
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