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F15803 Aldrich

Formamidine acetate salt

99%

Synonym: Formamidine acetic acid salt

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Properties

Related Categories Building Blocks, Chemical Synthesis, Imines/Amidines, Nitrogen Compounds, Organic Building Blocks More...
assay   99%
mp   158-161 °C (dec.)(lit.)

Description

Packaging

100, 500 g in poly bottle

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Formamidine acetate salt

purum, ≥98.0% (NT)

Formamidine-<SUP>13</SUP>C,d,<SUP>15</SUP>N<SUB>2</SUB> acetate

98 atom % D, 98 atom % 15N, 99 atom % 13C, 98% (CP)

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
WGK Germany 
2

Protocols & Articles

Peer-Reviewed Papers

References

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Comparative toxic and genotoxic effects of chloroacetanilides, formamidines and their degradation products on Vibrio fischeri and Chironomus riparius. Osano O, Admiraal W, Klamer HJ, et al. Environ. Pollut. 119(2), 195-202, (2002)

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A facile preparation of imidazolinium chlorides. Kuhn KM and Grubbs RH Org. Lett. 10(10), 2075-7, (2008)

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Potent nonclassical nucleoside antiviral drugs based on the N,N-diarylformamidine concept. Anastasi C, Hantz O, De Clercq E, et al. J. Med. Chem. 47(5), 1183-92, (2004)

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[Effects of occupational exposure to formamidines on cardiovascular functions]. Zhou Z, Hu Y, Kuang X, et al. Zhonghua Yu Fang Yi Xue Za Zhi 33(3), 140-2, (1999)

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Direct condensation of sulfonamide and formamide: NaI-catalyzed synthesis of N-sulfonyl formamidine using TBHP as oxidant. Chen S, Xu Y, and Wan X Org. Lett. 13(23), 6152-5, (2011)

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Nitrogen incorporation in CH(4)-N(2) photochemical aerosol produced by far ultraviolet irradiation. Trainer MG, Jimenez JL, Yung YL, et al. Astrobiology 12(4), 315-26, (2012)

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Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. Präsang C, Donnadieu B, and Bertrand G J. Am. Chem. Soc. 127(29), 10182-3, (2005)

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Selectivity of externally facing ion-binding sites in the Na/K pump to alkali metals and organic cations. Ratheal IM, Virgin GK, Yu H, et al. Proc. Natl. Acad. Sci. U. S. A. 107(43), 18718-23, (2010)

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Comparison of the reproductive biology between acaricide-resistant and acaricide-susceptible Rhipicephalus (Boophilus) microplus (Acari: Ixodidae). Davey RB, George JE, and Miller RJ Vet. Parasitol. 139(1-3), 211-20, (2006)

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Parallel synthesis of trisubstituted formamidines: a facile and versatile procedure. Porcheddu A, Giacomelli G, and Piredda I J. Comb. Chem. 11(1), 126-30, (2009)

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Alkoxyamine-derived formamidines: configurational control and molecular folding. Zhao W, Wang R, Mosey NJ, et al. Org. Lett. 13(19), 5160-3, (2011)

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First practical synthesis of formamidine ureas and derivatives. Ripka AS, Díaz DD, Sharpless KB, et al. Org. Lett. 5(9), 1531-3, (2003)

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Reaction products of W(CO)(6) with formamidines; electronic structure of a W(2)(mu-CO)(2) core with unsymmetric bridging carbonyls. Cotton FA, Donahue JP, Hall MB, et al. Inorg. Chem. 43(22), 6954-64, (2004)

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Relative stability of formamidine and carbamate groups in the bifunctional pesticide formetanate hydrochloride. Divito CB, Davies S, Masoudi S, et al. J. Agric. Food Chem. 55(14), 5377-82, (2007)

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Pharmacological characterization of a Bombyx mori alpha-adrenergic-like octopamine receptor stably expressed in a mammalian cell line. Huang J, Hamasaki T, and Ozoe Y Arch. Insect Biochem. Physiol. 73(2), 74-86, (2010)

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Synthesis and in solution and solid state structural study of intramolecular Pt...H interactions in pentafluorophenyl platinum(II) complexes containing the ligands triazene, formamidine, and 2-aminopyridine. Casas JM, Diosdado BE, Falvello LR, et al. Inorg. Chem. 44(25), 9444-52, (2005)

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Synthesis, X-ray crystallography characterization, vibrational spectroscopic, molecular electrostatic potential maps, thermodynamic properties studies of N,N'-di(p-thiazole)formamidine. Rofouei MK, Fereyduni E, Sohrabi N, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 78(1), 88-95, (2011)

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Modular synthesis of formamidines and their formation of stable organogels. Díaz DD and Finn MG Chem. Commun. (Camb.) (21), 2514-6, (2004)

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Synergistic actions of formamidine insecticides on the activity of pyrethroids and neonicotinoids against Aedes aegypti (Diptera: Culicidae). Ahmed MA and Matsumura F J. Med. Entomol. 49(6), 1405-10, (2012)

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The use of formamidine protection for the derivatization of aminobenzoic acids. Zhichkin PE, Peterson LH, Beer CM, et al. J. Org. Chem. 73(22), 8954-9, (2008)

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Linear and cyclic tetranuclear copper(I) complexes containing anions of N,N'-bis(pyrimidine-2-yl)formamidine. Chan ZK, Wu YY, Chen JD, et al. Dalton Trans. (5), 985-90, (2005)

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Thermal fluctuations and infrared spectra of the formamide-formamidine complex. Walewski L, Smaga A, Lesyng B, et al. J. Phys. Chem. A 116(42), 10412-9, (2012)

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Analogs of N'-hydroxy-N-(4H,5H-naphtho[1,2-d]thiazol-2-yl)methanimidamide inhibit Mycobacterium tuberculosis methionine aminopeptidases. Bhat S, Olaleye O, Meyer KJ, et al. Bioorg. Med. Chem. 20(14), 4507-13, (2012)

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Cytotoxicity and inhibitory properties against topoisomerase II of doxorubicin and its formamidine derivatives. Kik K, Studzian K, Wasowska-Łukawska M, et al. Acta Biochim. Pol. 56(1), 135-42, (2009)

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Cytotoxicity and cellular uptake of doxorubicin and its formamidine derivatives in HL60 sensitive and HL60/MX2 resistant cells. Kik K, Wasowska-Lukawska M, Oszczapowicz I, et al. Anticancer Res. 29(4), 1429-33, (2009)

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Fieser 1,403 / Fieser 2,202 / Fieser 3,147

FT-IR 1 (1), 815:B / FT-IR 2 (1), 1383:A / FT-NMR 1 (1), 1325:A / IR-Spectra (3), 484:C / IR-Spectra (2), 428:E / RegBook 1 (1), 959:G / Structure Index 1, 149:D:2

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