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P20009 Aldrich

Phenylboronic acid

95%

Synonym: Benzeneboronic acid, Dihydroxyphenylborane, NSC 66487, Phenyl-boric acid, Phenylboric acid, Phenyldihydroxyborane

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents,
InChI Key   HXITXNWTGFUOAU-UHFFFAOYSA-N
assay   95%
mp   216-219 °C(lit.)

Description

Other Notes

Contains varying amounts of phenylboronic anhydride

Packaging

10, 50, 250 g in poly bottle

Application

Reagent used for
• Rhodium-catalyzed intramolecular amination
• Pd-catalyzed direct arylation
• Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles
• Palladium-catalyzed stereoselective Heck-type reaction
• Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water

Reagent used in Preparation of
• Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions
• N-type polymers for all-polymer solar cells
• Novel series of potent and selective mTOR kinase inhibitors
• Inhibitors of lactate dehydrogenase against cancer cell proliferation

Price and Availability


KitAlysis - Increasing Catalysis Productivity

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
CY8575000
Protocols & Articles

Articles

Arylboronic Acids

Aldrich is pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give ...
Aldrich ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids - Aldrich ChemFiles 2007, 7.7, 3.

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

First cross-coupling reactions on halogenated 1H-1,2,4-triazole nucleosides

C-O activation of mesylates by a palladium catalyst and subsequent cross-coupling with potassium cyclopropyltrifluoroborate have been achieved with high yield. Both electron-enriched and electron- de...
Keywords: Chromatography, Cross couplings

Peer-Reviewed Papers
15

References

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