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P35405 Aldrich

Diphenyl sulfoxide

96%

Synonym: Phenyl sulfoxide

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfoxides, Sulfur Compounds More...
assay   96%
bp   206-208 °C/13 mmHg(lit.)
mp   69-71 °C(lit.)

Description

Packaging

25, 100 g in poly bottle

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Safety Information

WGK Germany 
3
RTECS 
DA9185000

Protocols & Articles

Peer-Reviewed Papers

References

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Ph2SO/Tf2O: a powerful promotor system in chemoselective glycosylations using thioglycosides. Codée JD, Litjens RE, den Heeten R, et al. Org. Lett. 5(9), 1519-22, (2003)

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Mechanistic studies on a sulfoxide transfer reaction mediated by diphenyl sulfoxide/triflic anhydride. Fascione MA, Adshead SJ, Mandal PK, et al. Chemistry 18(10), 2987-97, (2012)

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The fate of diphenyl sulphide, diphenyl sulphoxide and diphenyl sulphone in the rat. Mitchell SC, Nickson RM, Porter ER, et al. Drug Metabol. Drug Interact. 16(3), 191-206, (2000)

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Sulphoxide reduction by rat intestinal flora and by Escherichia coli in vitro. Lee SC and Renwick AG Biochem. Pharmacol. 49(11), 1567-76, (1995)

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Sulphoxide reduction by rat and rabbit tissues in vitro. Lee SC and Renwick AG Biochem. Pharmacol. 49(11), 1557-65, (1995)

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Disposition of diphenyl sulphoxide in rat. Mitchell SC, Gillham J, Jackson WF, et al. Xenobiotica 28(7), 715-22, (1998)

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Tunable stereoselectivity during sialylation using an N-acetyl-5-N,4-O-oxazolidinone-protected p-toluene 2-thio-sialoside donor with Tf(2)O/Ph(2)SO/TTBPy. Wang YJ, Jia J, Gu ZY, et al. Carbohydr. Res. 346(11), 1271-6, (2011)

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Efficient dehydrative sialylation of C-4-aminated sialyl-hemiketal donors with Ph2SO/Tf2O. Ye D, Liu W, Zhang D, et al. J. Org. Chem. 74(4), 1733-5, (2009)

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Photosensitized oxidation of alkyl phenyl sulfoxides. C-S bond cleavage in alkyl phenyl sulfoxide radical cations. Baciocchi E, Del Giacco T, Lanzalunga O, et al. J. Org. Chem. 73(15), 5675-82, (2008)

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Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane. Crich D and Li W Org. Lett. 8(5), 959-62, (2006)

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Diphenyl sulfoxides as selective antagonists of the muscarinic M2 receptor. Kozlowski JA, Lowe DB, Guzik HS, et al. Bioorg. Med. Chem. Lett. 10(20), 2255-7, (2000)

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Li⁺ selective podand-type fluoroionophore based on a diphenyl sulfoxide derivative bearing two pyrene groups. Nishimura Y, Takemura T, and Arai S Molecules 16(8), 6844-57, (2011)

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A facile one-pot benzylation of sodium enolates using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. Takuwa T, Minowa T, Fujisawa H, et al. Chem. Pharm. Bull. 53(5), 476-80, (2005)

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DNA cleavage by photolysis of aryl sulfoxides. Mayo DJ, Turner DP, Zucconi BE, et al. Bioorg. Med. Chem. Lett. 17(22), 6116-8, (2007)

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Kinetic and inhibition studies on reduction of diphenyl sulfoxide by guinea pig liver aldehyde oxidase. Yoshihara S and Tatsumi K Arch. Biochem. Biophys. 249(1), 8-14, (1986)

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Metabolism of diphenyl sulfoxide in perfused guinea pig liver. Involvement of aldehyde oxidase as a sulfoxide reductase. Yoshihara S and Tatsumi K Drug Metab. Dispos. 18(6), 876-81, (1990)

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Fluorescence emission mechanism and fluorescence properties of ternary Tb(III) complex with diphenyl sulphoxide and bipyridine. Li WX, Zheng YS, Chai WJ, et al. Luminescence 26(6), 754-61, (2011)

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[Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds]. Li WX, Wu GJ, Liu ZS, et al. Guang Pu Xue Yu Guang Pu Fen Xi 22(6), 905-7, (2002)

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[A novel synthetic approach of tryptophan-containing cystine peptides by regioselective disulfide bond-forming reaction using the silyl chloride-sulfoxide system]. Fujiwara Y Yakugaku Zasshi 120(2), 197-205, (2000)

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Beil. 6,IV,1489

Fieser 1,348

FT-IR 2 (2), 3206:D / FT-IR 1 (2), 483:B / FT-NMR 1 (2), 1578:A / IR-Spectra (2), 1000:A / IR-Spectra (3), 1148:A / NMR-Reference 2 (2), 806:A / RegBook 1 (2), 2183:D / Sax 6, 1241 / Structure Index 1, 343:D:1

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