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P45605 Aldrich

3,3-Dimethyl-2-butanone

98%

Synonym: α,α,α-Trimethylacetone, tert-Butyl methyl ketone, Pinacolone

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Properties

Related Categories Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones,
assay   98%
refractive index   n20/D 1.396(lit.)
bp   106 °C(lit.)
density   0.801 g/mL at 25 °C(lit.)

Description

Packaging

100, 500 mL in glass bottle

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1224BE 3 / PGII
WGK Germany 
2
RTECS 
EL7700000
Flash Point(F) 
41 °F
Flash Point(C) 
5 °C

Protocols & Articles

Peer-Reviewed Papers

References

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Isolation and characterization of 4-tert-butylphenol-utilizing Sphingobium fuliginis strains from Phragmites australis rhizosphere sediment. Toyama T, Momotani N, Ogata Y, et al. Appl. Environ. Microbiol. 76(20), 6733-40, (2010)

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Direct conversion of arylamines to pinacol boronates: a metal-free borylation process. Mo F, Jiang Y, Qiu D, et al. Angew. Chem. Int. Ed. Engl. 49(10), 1846-9, (2010)

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Pinacol coupling reaction of beta-halo-alpha,beta-unsaturated aldehydes promoted by TiI4. Shimizu M, Goto H, and Hayakawa R Org. Lett. 4(23), 4097-9, (2002)

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Hg(OTf)2-catalyzed vinylogous semi-pinacol rearrangement leading to 1,4-dihydroquinolines. Namba K, Kanaki M, Suto H, et al. Org. Lett. 14(5), 1222-5, (2012)

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Synthesis, spectroscopic, and in vitro photosensitizing efficacy of ketobacteriochlorins derived from ring-B and ring-D reduced chlorins via pinacol-pinacolone rearrangement. Joshi P, Ethirajan M, Goswami LN, et al. J. Org. Chem. 76(21), 8629-40, (2011)

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Coupling of enantioselective biooxidation of DL-1,2-propanediol and bioreduction of pinacolone via regeneration cycle of coenzyme. Gao K, Song Q, and Wei D Appl. Microbiol. Biotechnol. 71(6), 819-23, (2006)

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Effect of meso-substituents on the osmium tetraoxide reaction and pinacol-pinacolone rearrangement of the corresponding vic-dihydroxyporphyrins. Chen Y, Medforth CJ, Smith KM, et al. J. Org. Chem. 66(11), 3930-9, (2001)

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Enhancement of hepatic microsomal esterase activity following soman pretreatment in guinea pigs. Luttrell WE and Castle MC Biochem. Pharmacol. 46(11), 2083-92, (1993)

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Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot. Mishler RE, Biradar AV, Duncan CT, et al. Chem. Commun. (Camb.) (41), 6201-3, (2009)

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Merck 14,7440

Beil. 1,IV,3310

Aldrich MSDS 1, 1496:C / Corp MSDS 1 (2), 2839:C / FT-IR 1 (1), 405:D / FT-IR 2 (1), 641:A / FT-NMR 1 (1), 632:B / IR-Spectra (3), 240:C / IR-Spectra (2), 214:C / NMR-Reference 2 (1), 370:A / RegBook 1 (1), 447:F / Sax 6, 1141 / Structure Index 1, 64:A:2 / Vapor Phase 3, 487:C

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