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W366706 Aldrich

Diphenyl ether

≥99%

Synonym: Diphenyl oxide, Phenyl ether

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Properties

Related Categories A - D, A-D, Alphabetical Listings, C-D, Flavors and Fragrances,
biological source   synthetic
grade   Halal
  Kosher
  NI
vapor density   >5.86 (25 °C, vs air)
vapor pressure   <1 mmHg ( 20 °C)
assay   ≥99%
autoignition temp.   1144 °F
expl. lim.   1.5 %
refractive index   n20/D 1.579(lit.)
bp   259 °C(lit.)
mp   25-27 °C(lit.)
density   1.073 g/mL at 25 °C(lit.)
Organoleptic   geranium; green
allergen   no known allergens
Gene Information   human ... TTR(7276)

Description

Packaging

1 kg in glass bottle

10, 25 kg in poly drum

Other Notes

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Price and Availability


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Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
26-60-61
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
2
RTECS 
KN8970000
Flash Point(F) 
239 °F
Flash Point(C) 
115 °C

Protocols & Articles

Articles

Understanding the Complexities of Kosher Ingredients

Dr. Luke Grocholl, Quality Assurance Supervisor, Sigma-Aldrich Flavors & Fragrances and Rabbi Gershon Segal
Keywords: Fermentation, Food & Beverage, Safety industry

Peer-Reviewed Papers

References

Set your institution to view full text papers.

Measurement and modeling of diel variability of polybrominated diphenyl ethers and chlordanes in air. Moeckel C, Macleod M, Hungerbühler K, et al. Environ. Sci. Technol. 42(9), 3219-25, (2008)

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Surveying ubiquitin structure by noncovalent attachment of distance constrained bis(crown) ethers. Ly T, Liu Z, Pujanauski BG, et al. Anal. Chem. 80(13), 5059-64, (2008)

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Polybrominated diphenyl ether flame retardants in the North American environment. Hale RC, Alaee M, Manchester-Neesvig JB, et al. Environ. Int. 29(6), 771-9, (2003)

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Biodegradation of triclosan by a wastewater microorganism. Lee do G, Zhao F, Rezenom YH, et al. Water Res. 46(13), 4226-34, (2012)

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Synthesis and screening of mono- and di-aryl technetium and rhenium metallocarboranes. A new class of probes for the estrogen receptor. Patrick W Causey et al J. Med. Chem. 51, 2833-44, (2008)

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Activation and inhibition of leukotriene A4 hydrolase aminopeptidase activity by diphenyl ether and derivatives. Xiaolu Jiang et al Bioorg. Med. Chem. Lett. 18, 6549-52, (2008)

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Modulating the substrate specificity of LTA4H aminopeptidase by using chemical compounds and small-molecule-guided mutagenesis. Jiang X, Zhou L, Wu Y, et al. ChemBioChem. 11(8), 1120-8, (2010)

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Formation of toxic species and precursors of PCDD/F in thermal decomposition of alpha-cypermethrin. Summoogum SL, Mackie JC, Kennedy EM, et al. Chemosphere 85(2), 143-50, (2011)

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Determinants of prenatal exposure to polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) in an urban population. Herbstman JB, Sjödin A, Apelberg BJ, et al. Environ. Health Perspect. 115(12), 1794-800, (2007)

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Osteogenic activity of diphenyl ether-type cyclic diarylheptanoids derived from Acer nikoense. Yonezawa T, Lee JW, Akazawa H, et al. Bioorg. Med. Chem. Lett. 21(11), 3248-51, (2011)

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Versatile and fast gas chromatographic determination of frequently used brominated flame retardants in styrenic polymers. Pöhlein M, Bertran RU, Wolf M, et al. J. Chromatogr. A 1203(2), 217-28, (2008)

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Structure-activity relationships of diphenyl-ether as protoporphyrinogen oxidase inhibitors: insights from computational simulations. Hao GF, Tan Y, Yu NX, et al. J. Comput. Aided Mol. Des. 25(3), 213-22, (2011)

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Quenching of triplet benzophenone by benzene and diphenyl ether: a DFT study. Smith MJ and Bucher G J. Phys. Chem. A 114(39), 10712-6, (2010)

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Computational study of bond dissociation enthalpies for lignin model compounds. Substituent effects in phenethyl phenyl ethers. Beste A and Buchanan AC J. Org. Chem. 74(7), 2837-41, (2009)

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Mechanism and inhibition of saFabI, the enoyl reductase from Staphylococcus aureus. Xu H, Sullivan TJ, Sekiguchi J, et al. Biochemistry 47(14), 4228-36, (2008)

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Solvent effects on the hydrogenolysis of diphenyl ether with Raney nickel and their implications for the conversion of lignin. Wang X and Rinaldi R ChemSusChem 5(8), 1455-66, (2012)

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Synthesis, antitubercular activity and docking study of novel cyclic azole substituted diphenyl ether derivatives. Suvarna G Kini et al Eur. J. Med. Chem. 44, 492-500, (2009)

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Two-stage reduction/subsequent oxidation treatment of 2,2',4,4'-tetrabromodiphenyl ether in aqueous solutions: kinetic, pathway and toxicity. Luo S, Yang S, Xue Y, et al. J. Hazard. Mater. 192(3), 1795-803, (2011)

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Orally active, antimetastatic, nontoxic diphenyl ether-derived carbamoylphosphonate matrix metalloproteinase inhibitors. Frant J, Veerendhar A, Chernilovsky T, et al. ChemMedChem 6(8), 1471-7, (2011)

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Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Sergeev AG and Hartwig JF Science 332(6028), 439-43, (2011)

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Design, synthesis and evaluation of novel molecules with a diphenyl ether nucleus as potential antitubercular agents. Yinghong Yang et al Bioorg. Med. Chem. Lett. 22, 954-7, (2012)

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Overexpression of a specific soybean GmGSTU4 isoenzyme improves diphenyl ether and chloroacetanilide herbicide tolerance of transgenic tobacco plants. Benekos K, Kissoudis C, Nianiou-Obeidat I, et al. J. Biotechnol. 150(1), 195-201, (2010)

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Acute oral toxicity and liver oxidant/antioxidant stress of halogenated benzene, phenol, and diphenyl ether in mice: a comparative and mechanism exploration. Shi J, Feng M, Zhang X, et al. Environ. Sci. Pollut. Res. Int. 20(9), 6138-49, (2013)

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Macrocyclic oligoureas with xanthene and diphenyl ether units. Meshcheryakov D, Bolte M, and Böhmer V Org. Biomol. Chem. 7(21), 4386-90, (2009)

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Structure elucidation of three diphenyl ether derivatives from the mangrove endophytic fungus SBE-14 from the South China Sea. Liu F, Li Q, Yang H, et al. Magn. Reson. Chem. 47(5), 453-5, (2009)

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Synthesis and herbicidal activity of diphenyl ether derivatives containing unsaturated carboxylates. Yu H, Yang H, Cui D, et al. J. Agric. Food Chem. 59(21), 11718-26, (2011)

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Functional disorder of primary immunity responding to respiratory syncytial virus infection in offspring mice exposed to a flame retardant, decabrominated diphenyl ether, perinatally. Watanabe W, Shimizu T, Sawamura R, et al. J. Med. Virol. 82(6), 1075-82, (2010)

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Isolation and recovery of selected polybrominated diphenyl ethers from human serum and sheep serum: coupling reversed-phase solid-phase disk extraction and liquid-liquid extraction techniques with a capillary gas chromatographic electron capture negative ion mass spectrometric determinative technique. Loconto PR, Isenga D, O'Keefe M, et al. J. Chromatogr. Sci. 46(1), 53-60, (2008)

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Merck 14,7288

Beil. 6,IV,568

Arctander, 1081 / Corp MSDS 1 (2), 2778:A / FT-IR 2 (2), 1807:B / FT-IR 1 (1), 1056:C / FT-NMR 1 (2), 211:A / Fenaroli / IR-Spectra (2), 565:H / IR-Spectra (3), 634:H / NMR-Reference 2 (1), 852:A / RegBook 1 (1), 1245:A / RegBook 81 (1), 1245:A / Sax 6, 1234 / Structure Index 1, 190:C:7 / Vapor Phase 3, 987:C

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