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W366706 Aldrich

Diphenyl ether

≥99%, FG

Synonym: Diphenyl oxide, Phenyl ether

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Properties

Related Categories A - D, A-D, Alphabetical Listings, C-D, Flavors and Fragrances,
biological source   synthetic
grade   FG
  Halal
  Kosher
  NI
reg. compliance   FDA 21 CFR (110)
  EU Regulation 1334/2008 & 872/2012
vapor density   >5.86 (25 °C, vs air)
vapor pressure   <1 mmHg ( 20 °C)
assay   ≥99%
autoignition temp.   1144 °F
expl. lim.   1.5 %
refractive index   n20/D 1.579(lit.)
bp   259 °C(lit.)
mp   25-27 °C(lit.)
density   1.073 g/mL at 25 °C(lit.)
Organoleptic   geranium; green
food allergen   no known allergens
Gene Information   human ... TTR(7276)

Description

Packaging

1 kg in glass bottle

10, 25 kg in poly drum

Other Notes

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
2
RTECS 
KN8970000
Flash Point(F) 
239 °F
Flash Point(C) 
115 °C

Protocols & Articles

Articles

Understanding the Complexities of Kosher Ingredients

Dr. Luke Grocholl, Quality Assurance Supervisor, Sigma-Aldrich Flavors & Fragrances and Rabbi Gershon Segal
Keywords: Fermentation, Food & Beverage, Safety industry

Peer-Reviewed Papers

References

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Measurement and modeling of diel variability of polybrominated diphenyl ethers and chlordanes in air. Moeckel C, Macleod M, Hungerbühler K, et al. Environ. Sci. Technol. 42(9), 3219-25, (2008)

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Biodegradation of triclosan by a wastewater microorganism. Lee do G, Zhao F, Rezenom YH, et al. Water Res. 46(13), 4226-34, (2012)

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Synthesis and screening of mono- and di-aryl technetium and rhenium metallocarboranes. A new class of probes for the estrogen receptor. Patrick W Causey et al J. Med. Chem. 51, 2833-44, (2008)

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Polybrominated diphenyl ether flame retardants in the North American environment. Hale RC, Alaee M, Manchester-Neesvig JB, et al. Environ. Int. 29(6), 771-9, (2003)

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Determinants of prenatal exposure to polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) in an urban population. Herbstman JB, Sjödin A, Apelberg BJ, et al. Environ. Health Perspect. 115(12), 1794-800, (2007)

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Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Sergeev AG and Hartwig JF Science 332(6028), 439-43, (2011)

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Solvent effects on the hydrogenolysis of diphenyl ether with Raney nickel and their implications for the conversion of lignin. Wang X and Rinaldi R ChemSusChem 5(8), 1455-66, (2012)

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Structure-activity relationships of diphenyl-ether as protoporphyrinogen oxidase inhibitors: insights from computational simulations. Hao GF, Tan Y, Yu NX, et al. J. Comput. Aided Mol. Des. 25(3), 213-22, (2011)

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Formation of toxic species and precursors of PCDD/F in thermal decomposition of alpha-cypermethrin. Summoogum SL, Mackie JC, Kennedy EM, et al. Chemosphere 85(2), 143-50, (2011)

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Computational study of bond dissociation enthalpies for lignin model compounds. Substituent effects in phenethyl phenyl ethers. Beste A and Buchanan AC J. Org. Chem. 74(7), 2837-41, (2009)

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Osteogenic activity of diphenyl ether-type cyclic diarylheptanoids derived from Acer nikoense. Yonezawa T, Lee JW, Akazawa H, et al. Bioorg. Med. Chem. Lett. 21(11), 3248-51, (2011)

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Synthesis, antitubercular activity and docking study of novel cyclic azole substituted diphenyl ether derivatives. Suvarna G Kini et al Eur. J. Med. Chem. 44, 492-500, (2009)

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Versatile and fast gas chromatographic determination of frequently used brominated flame retardants in styrenic polymers. Pöhlein M, Bertran RU, Wolf M, et al. J. Chromatogr. A 1203(2), 217-28, (2008)

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Orally active, antimetastatic, nontoxic diphenyl ether-derived carbamoylphosphonate matrix metalloproteinase inhibitors. Frant J, Veerendhar A, Chernilovsky T, et al. ChemMedChem 6(8), 1471-7, (2011)

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Surveying ubiquitin structure by noncovalent attachment of distance constrained bis(crown) ethers. Ly T, Liu Z, Pujanauski BG, et al. Anal. Chem. 80(13), 5059-64, (2008)

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Mechanism and inhibition of saFabI, the enoyl reductase from Staphylococcus aureus. Xu H, Sullivan TJ, Sekiguchi J, et al. Biochemistry 47(14), 4228-36, (2008)

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Overexpression of a specific soybean GmGSTU4 isoenzyme improves diphenyl ether and chloroacetanilide herbicide tolerance of transgenic tobacco plants. Benekos K, Kissoudis C, Nianiou-Obeidat I, et al. J. Biotechnol. 150(1), 195-201, (2010)

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Two-stage reduction/subsequent oxidation treatment of 2,2',4,4'-tetrabromodiphenyl ether in aqueous solutions: kinetic, pathway and toxicity. Luo S, Yang S, Xue Y, et al. J. Hazard. Mater. 192(3), 1795-803, (2011)

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Synthesis and herbicidal activity of diphenyl ether derivatives containing unsaturated carboxylates. Yu H, Yang H, Cui D, et al. J. Agric. Food Chem. 59(21), 11718-26, (2011)

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Modulating the substrate specificity of LTA4H aminopeptidase by using chemical compounds and small-molecule-guided mutagenesis. Jiang X, Zhou L, Wu Y, et al. ChemBioChem. 11(8), 1120-8, (2010)

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Activation and inhibition of leukotriene A4 hydrolase aminopeptidase activity by diphenyl ether and derivatives. Xiaolu Jiang et al Bioorg. Med. Chem. Lett. 18, 6549-52, (2008)

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Acute oral toxicity and liver oxidant/antioxidant stress of halogenated benzene, phenol, and diphenyl ether in mice: a comparative and mechanism exploration. Shi J, Feng M, Zhang X, et al. Environ. Sci. Pollut. Res. Int. 20(9), 6138-49, (2013)

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Design, synthesis and evaluation of novel molecules with a diphenyl ether nucleus as potential antitubercular agents. Yinghong Yang et al Bioorg. Med. Chem. Lett. 22, 954-7, (2012)

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Structure elucidation of three diphenyl ether derivatives from the mangrove endophytic fungus SBE-14 from the South China Sea. Liu F, Li Q, Yang H, et al. Magn. Reson. Chem. 47(5), 453-5, (2009)

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Macrocyclic oligoureas with xanthene and diphenyl ether units. Meshcheryakov D, Bolte M, and Böhmer V Org. Biomol. Chem. 7(21), 4386-90, (2009)

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Quenching of triplet benzophenone by benzene and diphenyl ether: a DFT study. Smith MJ and Bucher G J. Phys. Chem. A 114(39), 10712-6, (2010)

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Functional disorder of primary immunity responding to respiratory syncytial virus infection in offspring mice exposed to a flame retardant, decabrominated diphenyl ether, perinatally. Watanabe W, Shimizu T, Sawamura R, et al. J. Med. Virol. 82(6), 1075-82, (2010)

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Isolation and recovery of selected polybrominated diphenyl ethers from human serum and sheep serum: coupling reversed-phase solid-phase disk extraction and liquid-liquid extraction techniques with a capillary gas chromatographic electron capture negative ion mass spectrometric determinative technique. Loconto PR, Isenga D, O'Keefe M, et al. J. Chromatogr. Sci. 46(1), 53-60, (2008)

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Merck 14,7288

Beil. 6,IV,568

Arctander, 1081 / Corp MSDS 1 (2), 2778:A / FT-IR 2 (2), 1807:B / FT-IR 1 (1), 1056:C / FT-NMR 1 (2), 211:A / Fenaroli / IR-Spectra (2), 565:H / IR-Spectra (3), 634:H / NMR-Reference 2 (1), 852:A / RegBook 1 (1), 1245:A / RegBook 81 (1), 1245:A / Sax 6, 1234 / Structure Index 1, 190:C:7 / Vapor Phase 3, 987:C

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