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Z233927 Aldrich

Oxford Chemistry Primers

No. 1, Organic Synthesis: The Roles of Boron and Silicon

  •  ISBN-10 0198556624

  •  ISBN-13 978-019855662-6

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publication info   S. Thomas, Oxford University Press, 1992, 96 pp., soft cover
mfr. no.   Oxford University Press

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Compounds of boron and silicon play a vital role in organic synthesis and the study of their properties and reactions is an important feature of undergraduate courses in organic chemistry. As part of the new, user-friendly Oxford Chemistry Primer Series, the essential chemistry of organoboranes and organosilanes is presented here with clarity and simplicity, emphasizing how these compounds can be used to provide simple solutions to a range of synthetic problems. With helpful study questions at the end of each part, and many suggestions for more advanced reading, this concise text provides undergraduates with an invaluable summary of an important topic in synthetic organic chemistry.

Table of Contents

1. Hydroboration
2. Reactions of Organoboranes 1
3. Reactions of Organoboranes 2
4. Organoboron Routes to Unsaturated Hydrocarbons
5. Allyl Boranes and Boron Enolates
6. Boronic Ester Homologation
7. Properties of Organosilicon Compounds
8. Protection of Alcohols as Silyl Ethers
9. Silyl Enol Ethers, Silyl Dienol Ethors, Silyl Ketene Acetals, and 1,2-Bis-Siloxy Alkenes
10. Alkene Synthesis
11. Vinyl Silanes
12. Allyl Silanes

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