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Z245682 Aldrich

Oxford Chemistry Primers

No. 10: Mechanisms of Reactions at Transition Metal Sites

  •  ISBN-10 0198557469

  •  ISBN-13 978-019855746-3



Related Categories Books and Software, Labware, Organic Chemistry Books More...
publication info   R. Henderson, Oxford University Press, 1994, 96 pp., soft cover
mfr. no.   Oxford University Press


General description

Understanding the mechanisms of the reactions at transition metal sites is a key component in designing synthetic methods, developing industrial homogeneous catalysts, and investigating metalloenzymes. These mechanisms are therefore an essential part of undergraduate chemistry courses. This primer provides a broad-based, systematic guide to the fundamentals of transition-metal mechanistic chemistry, including substitution, electron transfer, and reations of ligands. It serves as an ideal text for undergraduate students with a foundation in basic inorganic chemistry but who are new to inorganic reaction mechanisms

Table of Contents

1. Introduction to inorganic reaction mechanisms
PART I: Substitution Reactions
2. Substitution mechanisms at transition metal
3. Substitution at four-coordinate sites
4. Substitution at sites with coordination number greater than four
5. Catalysed substitution
PART II: Electron Transfer Reactions
6. Electron transfer reactions
7. The oxidative-addition reaction
PAT III: Ligand-Based Reactions
8. Activation of ligands
9. The insertion reaction

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