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Z256498 Aldrich

Chemistry Of Organic Fluorine Compounds: A Critical Review

  •  ISBN-10 084122515X

  •  ISBN-13 978-084122515-2

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publication info   M. Hudlicky and A. Pavlath, Oxford University Press, 1995, 1200 pp., hard cover
mfr. no.   American Chemical Society

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Provides complete coverage of the chemistry of organic fluorine compounds. Topics include fluorinating agents, fluorination processes, reactions of fluorinated compounds, modern analytical methods, and properties and applications of fluorinated compounds. Offers a critical review of the literature and provides over 4,500 references.

Table of Contents

Survey of the Literature of Organic Fluorine Chemistry
Survey of Fluorinating Agents
Methods of Introducing Fluorine into Organic Molecules: Addition of Fluorine,
Addition of Hydrogen Fluoride
Addition of Halogen Fluorides to Unsaturated Systems,
Addition of Fluorine and Other Elements,
Replacement of Hydrogen by Fluorine,
Replacement by Means of High-Valency Fluorides,
Electrophilic Fluorination of Carbon-Hydrogen Bonds,
Replacement of Halogens by Fluorine,
Replacement of Oxygen by Fluorine,
Replacement of Sulfur by Fluorine,
Replacement of Nitrogen by Fluorine,
Reactions of Organic Fluorine Compounds:
Reduction,
Oxidation,
Halogenation,
Nitration,
Nitrosation,
Sulfonation,
Acid-Catalyzed Syntheses,
Hydrolysis,
Alkylation,
Fluorocarbene Insertions,
Arylation,
Acylation,
Fluorinated Sulfur, Phosphorus, Boron, and Silicon Compounds,
Base-Catalyzed Condensation,
Reactions of Fluoromagnesium and Fluorolithium Compounds
Other Organometallic Syntheses,
Additions: Linear Additions across Double Bonds,
Linear Additions to Acetylenic Compounds,
Cycloadditions Forming Three- and Four-Membered Rings,
Cycloadditions Forming Five- and Six-membered Rings,
Addition Reactions across Polyfluoroalkyl- and Perfluoroalkyl-Substituted CO and CN Multiple Bond Systems
Eliminations,
Molecular Rearrangements andd Pyrolysis,
Fluorinated Compounds as Reagents,
Properties of Fluorinated Compounds:
Physical and Physicochemical Properties,
Biological Properties,
Analysis of Organic Fluorine Compounds
Destructive Analytical Methods,
Modern Methods of Separation, Identification, and Structure Determination,
Nuclear Magnetic Resonance Spectroscopy of Organofluorine Compounds,
Application of Fluorinated Compounds Refrigerants, Propellants, and Foam-Blowing Agents,
Fire Suppression Agents,
Organic Fluoropolymers,
Fluorinated Pharmaceuticals,
18F-Labeled Radiopharmaceuticals,
Fluorinated Anesthetics,
Perfluorinated Liquids in Biology and Medicine,
Fluorinated Ag

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