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Z278998 Aldrich

Handbook of Grignard Reagents

  •  ISBN-10 0824795458

  •  ISBN-13 978-082479545-0

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publication info   G. Silverman and P. Rakita, ed., Marcel Dekker, 1996, 736 pp., hard cover
mfr. no.   Marcel Dekker

Description

General description

This useful handbook provides the theoretical and practical information necessary to explore new applications for Grignard
reagents on a day-to-day basis. Presents a comprehensive overview of current research activities in Grignard chemistry.
Surveys specific reactions and applications of Grignard reagents, organized by type of substrate and the general category of reaction.

Table of Contents

Introduction
Methods of Grignard Reagent Preparation
Common Methods of Grignard Reagent Preparation
Preparation of Grignard Reagents from Olefins and Acetylenes
Magnesium Activation
Safe Handling Practices
Analyses of Grignard Reagents
Infrared and Raman Spectroscopy
Nuclear Magnetic Resonance Analysis of Grignard Reagents
Crystal Structures of Grignard Reagents
Mechanisms and Structure-Reactivity Relationships
Mechanism of Grignard Reagent Formulation
Mechanism of Reactions in Grignard Reagents
Structure-Reactivity Relationships
The Composition of Grignard Reagents in Solution: The Schlenk Equilibrium and Its Effect on Reactivity
Effect of Tris(pyrazolyl)hydrobotato Ligation
General Reaction of Grignard Reagents
Nucleophilic Substitution with Electrophilic Organic, Main Group, and Transition Metal Species
Nucleophilic Additions
Special Topics: Applications and Reactions of Grignard Reagents

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