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01324 Fluka

Acetonitrile

TraceSELECT®, for metal speciation analysis, ≥99.9%

Synonym: ACN, Methyl cyanide

  • CAS Number 75-05-8

  • Linear Formula CH3CN

  • Molecular Weight 41.05

  •  Beilstein Registry Number 741857

  •  EC Number 200-835-2

  •  MDL number MFCD00001878

  •  eCl@ss 39031501

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Properties

Related Categories Acetonitrile and Acetonitrile Solutions, Analytical Reagents, Analytical/Chromatography, Applications, Chromatography Reagents & Solvents,
vapor density   1.41 (vs air)
vapor pressure   72.8 mmHg ( 20 °C)
grade   TraceSELECT®
assay   ≥99.9%
autoignition temp.   973 °F
quality   for metal speciation analysis
expl. lim.   16 %
impurities   ≤0.01% water (Karl Fischer)
transmittance   195 nm, ≥80%
  200 nm, ≥95%
  230 nm, 99%
refractive index   n20/D 1.344(lit.)
bp   81-82 °C(lit.)
mp   −48 °C(lit.)
density   0.786 g/mL at 25 °C(lit.)
anion traces   bromide (Br-): ≤10 μg/kg
  chloride (Cl-): ≤25 μg/kg
  fluoride (F-): ≤10 μg/kg
  iodide (I-): ≤10 μg/kg
  nitrate (NO3-): ≤25 μg/kg
  nitrite (NO2-): ≤10 μg/kg
  phosphate (PO43-): ≤10 μg/kg
  sulfate (SO42-): ≤10 μg/kg
cation traces   Ag: ≤0.5 μg/kg
  Al: ≤1 μg/kg
  As: ≤1 μg/kg
  Au: ≤0.5 μg/kg
  Ba: ≤0.5 μg/kg
  Be: ≤0.5 μg/kg
  Bi: ≤0.5 μg/kg
  Ca: ≤20 μg/kg
  Cd: ≤0.5 μg/kg
  Ce: ≤0.5 μg/kg
  Co: ≤0.5 μg/kg
  Cr: ≤1 μg/kg
  Cs: ≤0.5 μg/kg
  Cu: ≤1 μg/kg
  Fe: ≤1 μg/kg
  Ga: ≤0.5 μg/kg
  Ge: ≤0.5 μg/kg
  Hg: ≤0.5 μg/kg
  In: ≤0.5 μg/kg
  Ir: ≤0.5 μg/kg
  K: ≤10 μg/kg
  Li: ≤0.5 μg/kg
  Mg: ≤1 μg/kg
  Mn: ≤0.5 μg/kg
  Mo: ≤0.5 μg/kg
  Na: ≤50 μg/kg
  Ni: ≤1 μg/kg
  Pb: ≤0.5 μg/kg
  Pd: ≤0.5 μg/kg
  Pt: ≤0.5 μg/kg
  Rb: ≤0.5 μg/kg
  Rh: ≤0.5 μg/kg
  Ru: ≤0.5 μg/kg
  Sb: ≤0.5 μg/kg
  Se: ≤1 μg/kg
  Sn: ≤0.5 μg/kg
  Sr: ≤0.5 μg/kg
  Ti: ≤1 μg/kg
  Tl: ≤0.5 μg/kg
  V: ≤0.5 μg/kg
  Zn: ≤1 μg/kg
  Zr: ≤0.5 μg/kg

Description

Application

high purity grade for ICP-MS detection

Legal Information

FLUKA is a registered trademark of Honeywell Specialty Chemicals Seelze GmbH

TraceSELECT is a registered trademark of Honeywell Specialty Chemicals Seelze GmbH

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1648 3 / PGII
WGK Germany 
2
RTECS 
AL7700000
Flash Point(F) 
35.6 °F
Flash Point(C) 
2 °C
Protocols & Articles
Peer-Reviewed Papers

References

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Stability of extemporaneously compounded dexamethasone in glass and plastic bottles and plastic syringes. Ensom MH, Décarie D, et al. Can. J. Hosp. Pharm. 67(4), 274-9, (2014)

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Comparative evaluation of seven different sample treatment approaches for large-scale multiclass sport drug testing in urine by liquid chromatography-mass spectrometry. Domínguez-Romero JC, García-Reyes JF, Molina-Díaz A, et al. J. Chromatogr. A. 1361, 34-42, (2014)

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Ionic liquid intercalated clay sorbents for micro solid phase extraction of steroid hormones from water samples with analysis by liquid chromatography-tandem mass spectrometry. Aftafa C, Pelit FO, Yalçinkaya EE, et al. J. Chromatogr. A. 1361, 43-52, (2014)

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An in vivo microdialysis study of FLZ penetration through the blood-brain barrier in normal and 6-hydroxydopamine induced Parkinson's disease model rats. Hou J, Liu Q, Li Y, et al. Biomed Res. Int. 2014, 850493, (2014)

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Molecularly imprinted polymer for specific extraction of hypericin from Hypericum perforatum L. herbal extract. Li Z, Qin C, Li D, et al. J. Pharm. Biomed. Anal. 98, 210-20, (2014)

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Qualitative and quantitative determination of peptides related to celiac disease in mixtures derived from different methods of simulated gastrointestinal digestion of wheat products. Prandi B, Faccini A, Tedeschi T, et al. Anal. Bioanal. Chem 406(19), 4765-75, (2014)

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Application of fluorescence two-dimensional difference in-gel electrophoresis as a proteomic biomarker discovery tool in muscular dystrophy research. Carberry S, Zweyer M, Swandulla D, et al. Biology (Basel.) 2(4), 1438-64, (2014)

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Pharmacokinetic and pharmacodynamic analysis of inosine monophosphate dehydrogenase activity in hematopoietic cell transplantation recipients treated with mycophenolate mofetil. Li H, Mager DE, Sandmaier BM, et al. Biol. Blood Marrow Transplant. 20(8), 1121-9, (2014)

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High-performance electrocatalysis using metallic cobalt pyrite (CoS?) micro- and nanostructures. Faber MS, Dziedzic R, Lukowski MA, et al. J. Am. Chem. Soc. 136(28), 10053-61, (2014)

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Flavonol glycosides and other phenolic compounds in buds and leaves of different varieties of black currant (Ribes nigrum L.) and changes during growing season. Liu P, Kallio H, Yang B, et al. Food Chem. 160, 180-9, (2014)

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Sitagliptin, a DPP-4 inhibitor, acutely inhibits intestinal lipoprotein particle secretion in healthy humans. Xiao C, Dash S, Morgantini C, et al. Diabetes 63(7), 2394-401, (2014)

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Hippocampal Lewy pathology and cholinergic dysfunction are associated with dementia in Parkinson's disease. Hall H, Reyes S, Landeck N, et al. Brain 137(Pt 9), 2493-508, (2014)

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Evaluation of matrix-assisted laser desorption ionization-time of flight mass spectrometry for species identification of Acinetobacter strains isolated from blood cultures. Kishii K, Kikuchi K, Matsuda N, et al. Clin. Microbiol. Infect. 20(5), 424-30, (2014)

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Glycosylation profiles determine extravasation and disease-targeting properties of armed antibodies. Venetz D, Hess C, Lin CW, et al. Proc. Natl. Acad. Sci. U. S. A. 112(7), 2000-5, (2015)

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Cationic liposomes loaded with a synthetic long peptide and poly(I:C): a defined adjuvanted vaccine for induction of antigen-specific T cell cytotoxicity. Varypataki EM, van der Maaden K, Bouwstra J, et al. AAPS J. 17(1), 216-26, (2015)

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Analysis of changes in SUMO-2/3 modification during breast cancer progression and metastasis. Subramonian D, Raghunayakula S, Olsen JV, et al. J. Proteome Res. 13(9), 3905-18, (2014)

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Anti-staphylococcal activity of C-methyl flavanones from propolis of Australian stingless bees (Tetragonula carbonaria) and fruit resins of Corymbia torelliana (Myrtaceae). Massaro CF, Katouli M, Grkovic T, et al. Fitoterapia 95, 247-57, (2014)

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Evidence-based morphine dosing for postoperative neonates and infants. Krekels EH, Tibboel D, de Wildt SN, et al. Clin. Pharmacokinet. 53(6), 553-63, (2014)

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A role for oleoylethanolamide in chronic lymphocytic leukemia. Masoodi M, Lee E, Eiden M, et al. Leukemia 28(7), 1381-7, (2014)

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CYP2C9 genotype vs. metabolic phenotype for individual drug dosing--a correlation analysis using flurbiprofen as probe drug. Vogl S, Lutz RW, Schönfelder G, et al. PLoS ONE 10(3), e0120403, (2015)

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Oil accumulation by the oleaginous diatom Fistulifera solaris as revealed by the genome and transcriptome. Tanaka T, Maeda Y, Veluchamy A, et al. Plant Cell 27(1), 162-76, (2015)

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Increased levels of IL-6 in the cerebrospinal fluid of patients with chronic schizophrenia--significance for activation of the kynurenine pathway. Schwieler L, Larsson MK, Skogh E, et al. J. Psychiatry Neurosci. 40(2), 126-33, (2015)

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Natural genetic variation impacts expression levels of coding, non-coding, and antisense transcripts in fission yeast. Clément-Ziza M, Marsellach FX, Codlin S, et al. Mol. Syst. Biol. 10, 764, (2014)

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High warfarin sensitivity in carriers of CYP2C9*35 is determined by the impaired interaction with P450 oxidoreductase. Lee MY, Borgiani P, Johansson I, et al. Pharmacogenomics J. 14(4), 343-9, (2014)

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Revisiting the arthritogenic peptide theory: quantitative not qualitative changes in the peptide repertoire of HLA-B27 allotypes. Schittenhelm RB, Sian TC, Wilmann PG, et al. Arthritis Rheumatology 67(3), 702-13, (2015)

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Amyloid-beta-activated human microglial cells through ER-resident proteins. Yoo Y, Byun K, Kang T, et al. J. Proteome Res. 14(1), 214-23, (2015)

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HepaRG cells as human-relevant in vitro model to study the effects of inflammatory stimuli on cytochrome P450 isoenzymes. Rubin K, Janefeldt A, Andersson L, et al. Drug Metab. Dispos. 43(1), 119-25, (2014)

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Identification of N-linked glycosylation and putative O-fucosylation, C-mannosylation sites in plasma derived ADAMTS13. Sorvillo N, Kaijen PH, Matsumoto M, et al. J. Thromb. Haemost. 12(5), 670-9, (2014)

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Prediction of the zeta potentials and ionic descriptors of a silica hydride stationary phase with mobile phases of different pH and ionic strength. Kulsing C, Yang Y, Matyska MT, et al. Anal. Chim. Acta 859, 79-86, (2015)

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Integrated omic analysis of lung cancer reveals metabolism proteome signatures with prognostic impact. Li L, Wei Y, To C, et al. Nat. Commun. 5, 5469, (2014)

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Efflux by small multidrug resistance proteins is inhibited by membrane-interactive helix-stapled peptides. Bellmann-Sickert K, Stone TA, Poulsen BE, et al. J. Biol. Chem. 290(3), 1752-9, (2015)

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Directed evolution of new and improved enzyme functions using an evolutionary intermediate and multidirectional search. Porter JL, Boon PL, Murray TP, et al. ACS Chem. Biol. 10(2), 611-21, (2015)

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Steroid profiling reveals widespread local regulation of glucocorticoid levels during mouse development. Taves MD, Plumb AW, Sandkam BA, et al. Endocrinology 156(2), 511-22, (2015)

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Integrated omic analysis of oropharyngeal carcinomas reveals human papillomavirus (HPV)-dependent regulation of the activator protein 1 (AP-1) pathway. Sepiashvili L, Waggott D, Hui A, et al. Mol. Cell. Proteomics 13(12), 3572-84, (2014)

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Serum and adipose tissue amino acid homeostasis in the metabolically healthy obese. Badoud F, Lam KP, DiBattista A, et al. J. Proteome Res. 13(7), 3455-66, (2014)

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Nanostructural morphology of plasticized wheat gluten and modified potato starch composites: relationship to mechanical and barrier properties. Muneer F, Andersson M, Koch K, et al. Biomacromolecules 16(3), 695-705, (2015)

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Tuning temperature responsive poly(2-alkyl-2-oxazoline)s by supramolecular host-guest interactions. de la Rosa VR, Nau WM, Hoogenboom R, et al. Org. Biomol. Chem. 13(10), 3048-57, (2015)

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A simple LC-MS/MS method using HILIC chromatography for the determination of fosfomycin in plasma and urine: application to a pilot pharmacokinetic study in humans. Parker SL, Lipman J, Roberts JA, et al. J. Pharm. Biomed. Anal. 105, 39-45, (2015)

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Large-scale analysis of lysine SUMOylation by SUMO remnant immunoaffinity profiling. Lamoliatte F, Caron D, Durette C, et al. Nat. Commun. 5, 5409, (2014)

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CTX-M-1 ?-lactamase expression in Escherichia coli is dependent on cefotaxime concentration, growth phase and gene location. Kjeldsen TS, Overgaard M, Nielsen SS, et al. J. Antimicrob. Chemother. 70(1), 62-70, (2014)

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Evaluation and comparison of the kinetic performance of ultra-high performance liquid chromatography and high-performance liquid chromatography columns in hydrophilic interaction and reversed-phase liquid chromatography conditions. Song H, Adams E, Desmet G, et al. J. Chromatogr. A. 1369, 83-91, (2014)

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A dual inhibitor of matrix metalloproteinases and a disintegrin and metalloproteinases, [¹?F]FB-ML5, as a molecular probe for non-invasive MMP/ADAM-targeted imaging. Matusiak N, Castelli R, Tuin AW, et al. Bioorg. Med. Chem. 23(1), 192-202, (2014)

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AGE-modified basement membrane cooperates with Endo180 to promote epithelial cell invasiveness and decrease prostate cancer survival. Rodriguez-Teja M, Gronau JH, Breit C, et al. J. Pathol. 235(4), 581-92, (2015)

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The Fusarium graminearum genome reveals more secondary metabolite gene clusters and hints of horizontal gene transfer. Sieber CM, Lee W, Wong P, et al. PLoS ONE 9(10), e110311, (2014)

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Pharmacokinetics of intravenous, plain oral and enteric-coated oral omeprazole in the horse. Sykes BW, Underwood C, McGowan CM, et al. J. Vet. Pharmacol. Ther. 38(2), 130-6, (2015)

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Estimation of the effects of longitudinal temperature gradients caused by frictional heating on the solute retention using fully porous and superficially porous sub-2?m materials. Fekete S, Fekete J, Guillarme D, et al. J. Chromatogr. A. 1359, 124-30, (2014)

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Human and simulated intestinal fluids as solvent systems to explore food effects on intestinal solubility and permeability. Stappaerts J, Wuyts B, Tack J, et al. Eur. J. Pharm. Sci. 63, 178-86, (2014)

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Merck 14,70

Beil. 2,IV,419

Fieser 2,13

Aldrich MSDS 1, 13:C / Corp MSDS 1 (1), 22:A / FT-IR 2 (1), 1422:A / FT-IR 1 (1), 837:A / FT-NMR 1 (1), 1351:A / IR-Spectra (3), 1527:A / IR-Spectra (2), 444:A / IR-Spectra (3), 500:A / NMR-Reference 2 (1), 695:A / RegBook 1 (1), 987:A / Sax 6, 90 / Sigma FT-IR 1 (2), 233:C / Structure Index 1, 154:A:1 / Vapor Phase 3, 795:A

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