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Ethylenediamine

puriss. p.a., absolute, ≥99.5% (GC)

Synonym: 1,2-Diaminoethane

  • CAS Number 107-15-3

  • Linear Formula NH2CH2CH2NH2

  • Molecular Weight 60.10

  •  Beilstein Registry Number 605263

  •  EC Number 203-468-6

  •  MDL number MFCD00008204

  •  PubChem Substance ID 24845499

  •  eCl@ss 39030201

  • Popular Documents:  FTNMR (PDF)  

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Properties

Related Categories Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, E-H, Puriss p.a., Puriss p.a. More...
vapor density   2.07 (vs air)
vapor pressure   10 mmHg ( 20 °C)
grade   absolute
  puriss. p.a.
assay   ≥99.5% (GC)
autoignition temp.   716 °F
expl. lim.   16 %
impurities   ≤0.5% water
refractive index   n20/D 1.456
  n20/D 1.4565(lit.)
bp   118 °C(lit.)
mp   8.5 °C(lit.)
density   0.899 g/mL at 25 °C(lit.)
cation traces   Ca: ≤5 mg/kg
  Cd: ≤1 mg/kg
  Co: ≤1 mg/kg
  Cr: ≤1 mg/kg
  Cu: ≤1 mg/kg
  Fe: ≤1 mg/kg
  K: ≤20 mg/kg
  Mg: ≤1 mg/kg
  Mn: ≤1 mg/kg
  Na: ≤20 mg/kg
  Ni: ≤1 mg/kg
  Pb: ≤1 mg/kg
  Zn: ≤1 mg/kg
Gene Information   human ... FNTA(2339)

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Safety & Documentation

Safety Information

Signal word 
Danger
Precautionary statements 
RIDADR 
UN 1604 3(8) / PGII
WGK Germany 
2
RTECS 
KH8575000
Flash Point(F) 
100.4 °F
Flash Point(C) 
38 °C

Protocols & Articles

Articles

Determination of Water Content in 1,2-Diaminoethane (Ethylene diamine) Using Karl Fischer Titration

The determination of water in 1,2-diaminoethane presents two different sorts of difficulties: 1. The compound reacts strongly alkaline and it shifts the pH of the medium in the titration vessel to an...
Keywords: Methylations, Pharmaceutical, Solvents, Titrations

Peer-Reviewed Papers

References

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Inulin-Ethylenediamine Coated SPIONs Magnetoplexes: A Promising Tool for Improving siRNA Delivery. Licciardi M, Li Volsi A, Sardo C, et al. Pharm. Res., (2015)

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Absorption of carbon dioxide into aqueous solutions of ethylenediamine: Effect of interfacial turbulence. Sada E, et al. Chem. Eng. J. 13(3), 213-17, (1977)

Mild synthesis of ultra-small CdSe quantum dots in ethylenediamine solution. Yoon J-H, et al. Mater. Lett. 59(11), 1430-33, (2005)

Structure-directing coordination template effect of ethylenediamine in formations of ZnS and ZnSe nanocrystallites via solvothermal route. Deng ZX, et al. Inorg. Chem. 41(4), 869-873, (2002)

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Ethylenediamine, profile of a sensitizing excipient. Zuidema J Pharm. Weekbl. Sci. 7(4), 134-40, (1985)

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Am(m)ines make the difference: organoruthenium am(m)ine complexes and their chemistry in anticancer drug development. Babak MV, Meier SM, Legin AA, et al. Chemistry 19(13), 4308-18, (2013)

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[Allergic dermatitis caused by contact with ethylenediamine]. Balato N, Cusano F, Lembo G, et al. G. Ital. Dermatol. Venereol. 122(11), 583-8, (1987)

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[A case of aminophylline hypersensitivity reaction due to ethylenediamine]. Yoshizawa A, Araki Y, Kobayashi N, et al. Arerugi. 48(11), 1206-11, (1999)

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An orally delivered small-molecule formulation with antiangiogenic and anticancer activity. Benny O Nat. Biotechnol. 26(7), 799-807, (2008)

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A sensor tip based on carbon nanotube-ink printed electrode for the dengue virus NS1 protein. Dias AC, Gomes-Filho SL, Silva MM, et al. Biosens. Bioelectron. 44, 216-21, (2013)

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Amine functionalized graphene oxide/CNT nanocomposite for ultrasensitive electrochemical detection of trinitrotoluene. Sablok K, Bhalla V, Sharma P, et al. J. Hazard. Mater. 248-249, 322-8, (2013)

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A critical reinvestigation of the TAED-activated peroxide system for low-temperature bleaching of cotton. Xu C, Long X, Du J, et al. Carbohydr. Polym. 92(1), 249-53, (2013)

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Nonfouling hydrophilic poly(ethylene glycol) engraftment strategy for PDMS/SU-8 heterogeneous microfluidic devices. Yeh PY, Zhang Z, Lin M, et al. Langmuir 28(46), 16227-36, (2012)

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A re-investigation of the Mark-Houwink-Sakurada parameters for cellulose in Cuen: a study based on size-exclusion chromatography combined with multi-angle light scattering and viscometry. Kes M and Christensen BE J. Chromatogr. A 1281, 32-7, (2013)

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Remediation of Cu(II), Ni(II), and Cr(III) ions from simulated wastewater by dendrimer/titania composites. Barakat MA, Ramadan MH, Alghamdi MA, et al. J. Environ. Manage. 117, 50-7, (2013)

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Synthesis and X-ray structures of novel macrocycles and macrobicycles containing N,N-di(pyrrolylmethyl)-N-methylamine moiety: preliminary anion binding study. Kumar R, Guchhait T, and Mani G Inorg. Chem. 51(16), 9029-38, (2012)

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Synthesis of ethylenediamine modified chitosan and evaluation for removal of divalent metal ions. Chethan PD and Vishalakshi B Carbohydr. Polym. 97(2), 530-6, (2013)

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New hyaluronic acid based brush copolymers synthesized by atom transfer radical polymerization. Pitarresi G, Fiorica C, Licciardi M, et al. Carbohydr. Polym. 92(2), 1054-63, (2013)

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Competitive binding sites of a ruthenium arene anticancer complex on oligonucleotides studied by mass spectrometry: ladder-sequencing versus top-down. Wu K, Hu W, Luo Q, et al. J. Am. Soc. Mass Spectrom. 24(3), 410-20, (2013)

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The role of the helper lipid dioleoylphosphatidylethanolamine (DOPE) for DNA transfection cooperating with a cationic lipid bearing ethylenediamine. Mochizuki S, Kanegae N, Nishina K, et al. Biochim. Biophys. Acta 1828(2), 412-8, (2013)

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Synthesis of novel octa-cationic and non-ionic 1,2-ethanediamine substituted zinc (Ⅱ) phthalocyanines and their in vitro anti-cancer activity comparison. Wang A, Zhou L, Fang K, et al. Eur. J. Med. Chem. 58, 12-21, (2012)

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Ethylenediamine diacetate (EDDA) mediated synthesis of aurones under ultrasound: their evaluation as inhibitors of SIRT1. Manjulatha K, Srinivas S, Mulakayala N, et al. Bioorg. Med. Chem. Lett. 22(19), 6160-5, (2012)

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Autofluorescence generation and elimination: a lesson from glutaraldehyde. Lee K, Choi S, Yang C, et al. Chem. Commun. (Camb.) 49(29), 3028-30, (2013)

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Synthesis and DNA interaction of ethylenediamine platinum(II) complexes linked to DNA intercalants. Duskova K, Sierra S, Fernández MJ, et al. Bioorg. Med. Chem. 20(24), 7112-8, (2012)

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Degradable poly(amidoamine) hydrogels as scaffolds for in vitro culturing of peripheral nervous system cells. Mauro N, Manfredi A, Ranucci E, et al. Macromol. Biosci. 13(3), 332-47, (2013)

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Photoluminescence of silicon quantum dots in nanospheres. Zhang Y, Han X, Zhang J, et al. Nanoscale 4(24), 7760-5, (2012)

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Synthesis and spectral studies on Pb(II) dithiocarbamate complexes containing benzyl and furfuryl groups and their use as precursors for PbS nanoparticles. Sathiyaraj E and Thirumaran S Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 97, 575-81, (2012)

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Structural and functional characteristics of xenavidin, the first frog avidin from Xenopus tropicalis. Määttä JA, Helppolainen SH, Hytönen VP, et al. BMC Struct. Biol. 9, 63, (2009)

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Accessibility and selective stabilization of the principal spin states of iron by pyridyl versus phenolic ketimines: modulation of the 6A1 ↔ 2T2 ground-state transformation of the [FeN4O2]+ chromophore. Shongwe MS, Al-Zaabi UA, Al-Mjeni F, et al. Inorg. Chem. 51(15), 8241-53, (2012)

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Nitric oxide reactivity of Cu(II) complexes of tetra- and pentadentate ligands: structural influence in deciding the reduction pathway. Kumar P, Kalita A, and Mondal B Dalton Trans. 42(16), 5731-9, (2013)

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Influence of different length spacers containing enzyme conjugate on functional parameters of progesterone ELISA. Shrivastav TG, Chaube SK, Kariya KP, et al. J. Immunoassay Immunochem. 34(1), 94-108, (2013)

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Capillary electrophoresis of heparin and other glycosaminoglycans using a polyamine running electrolyte. Loegel TN, Trombley JD, Taylor RT, et al. Anal. Chim. Acta 753, 90-6, (2012)

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Platinum(II) complexes containing long-chain hydrophobic N-alkyl-diamine ligands: synthesis, characterization, molecular modeling, and cytotoxic activity. Tavares TT, Teixeira GF, Lopes CM, et al. J. Inorg. Biochem. 115, 13-9, (2012)

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Interaction of drug based binuclear mixed-ligand complexes with DNA. Mohan N Patel et al Bioorg. Med. Chem. 17, 5648-55, (2009)

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Novel pyranopyrazoles: synthesis and theoretical studies. Al-Amiery AA, Al-Bayati RI, Saed FM, et al. Molecules 17(9), 10377-89, (2012)

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Spectroscopic and electrochemical characterization of some Schiff base metal complexes containing benzoin moiety. El-Shahawi MS, Al-Jahdali MS, Bashammakh AS, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 113, 459-65, (2013)

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Antitubercular activity of alpha,omega-diaminoalkanes, H2N(CH2)nNH2. Fátima M F Vergara et al Bioorg. Med. Chem. Lett. 19, 4937-8, (2009)

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Aging effects of plasma polymerized ethylenediamine (PPEDA) thin films on cell-adhesive implant coatings. Testrich H, Rebl H, Finke B, et al. Mater. Sci. Eng. C. Mater. Biol. Appl. 33(7), 3875-80, (2013)

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In vivo examination of the local inflammatory response after implantation of Ti6Al4V samples with a combined low-temperature plasma treatment using pulsed magnetron sputtering of copper and plasma-polymerized ethylenediamine. Hoene A, Patrzyk M, Walschus U, et al. J. Mater. Sci. Mater. Med. 24(3), 761-71, (2013)

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Allergic contact dermatitis to ethylenediamine. A continuing problem. Hogan DJ Dermatol. Clin. 8(1), 133-6, (1990)

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Effects of ethylenediamine in rodent models of seizure, motor coordination and anxiety. Addae JI, Walkins K, Cruickshank R, et al. Brain Res. 1473, 155-60, (2012)

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Cytotoxic activity of N, N'-Bis (2-hydroxybenzyl) ethylenediamine derivatives in human cancer cell lines. Musa MA, Badisa VL, and Latinwo LM Anticancer Res. 34(4), 1601-7, (2014)

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Merck 14,3795

Beil. 4,IV,1166

Fieser 1,372 / Fieser 4,231 / Fieser 10,297 / Fieser 12,338 / Fieser 13,157

Aldrich MSDS 1, 902:D / Corp MSDS 1 (1), 1604:B / FT-IR 2 (1), 453:C / FT-IR 1 (1), 289:C / FT-NMR 1 (1), 463:B / IR-Spectra (2), 154:A / IR-Spectra (3), 171:A / NMR-Reference 2 (1), 248:A / RegBook 1 (1), 309:A / Sax 6, 1303 / Sigma FT-IR 1 (2), 547:A / Structure Index 1, 42:A:3 / Vapor Phase 3, 374:D

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