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14715 Fluka

(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine-manganese(III) chloride

purum, ≥96.0% (CHN)

Synonym: (R,R)-Jacobsen’s catalyst

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Properties

grade   purum
assay   ≥96.0% (CHN)

Description

Other Notes

Catalyst for the enantioselective epoxidation of olefins lacking functional groups1,2; Catalyst for enantioselective hydrolysis of epoxides3

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Safety & Documentation

Safety Information

WGK Germany 
3

Protocols & Articles

Peer-Reviewed Papers

References

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1. S. Chang et al. Tetrahedron 58, 6939, (1993)

2. E.N. Jacobsen et al. Tetrahedron 50, 4323, (1994)

3. Practical Access to Highly Enantioenriched C-3 Building Blocks via Hydrolytic Kinetic Resolution. M.E. Furrow et al. J. Org. Chem. 63, 6776, (1998)

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Merck 14,5252

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404446 (R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

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