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17843 Fluka

Ammonium formate

for HPLC, ≥99.0%

Synonym: Formic acid ammonium salt

  • CAS Number 540-69-2

  • Linear Formula HCO2NH4

  • Molecular Weight 63.06

  •  Beilstein Registry Number 3625095

  •  EC Number 208-753-9

  •  MDL number MFCD00013103

  •  PubChem Substance ID 24850743

  •  eCl@ss 39021903

  • Popular Documents:  FTIR (PDF)  

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Properties

Related Categories Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reagents & Solvents, HPLC,
grade   for HPLC
assay   ≥99.0% (dried material, NT)
  ≥99.0%
impurities   ≤2% water
pH   5.5-7.5 (20 °C, 10% in H2O)
mp   119-121 °C(lit.)
solubility   H2O: soluble0.1 g/mL at 25 °C, clear, colorless
density   1.26 g/mL at 25 °C(lit.)
λ   10 % in H2O
UV absorption   λ: 250 nm Amax: 0.05
  λ: 260 nm Amax: 0.04
  λ: 270 nm Amax: 0.03
  λ: 280 nm Amax: 0.02
  λ: 500 nm Amax: 0.02
suitability   corresponds for filter test
  corresponds to standard for RP gradient test

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
WGK Germany 
1
RTECS 
BQ6650000

Protocols & Articles

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Peer-Reviewed Papers

References

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Acidification due to microbial dechlorination near a trichloroethene DNAPL is overcome with pH buffer or formate as electron donor: experimental demonstration in diffusion-cells. Philips J, Maes N, Springael D, et al. J. Contam. Hydrol. 147, 25-33, (2013)

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Monoclonal antibodies selective for α-synuclein oligomers/protofibrils recognize brain pathology in Lewy body disorders and α-synuclein transgenic mice with the disease-causing A30P mutation. Fagerqvist T, Lindström V, Nordström E, et al. J. Neurochem. 126(1), 131-44, (2013)

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Density functional theory study on the adsorption and decomposition of the formic acid catalyzed by highly active mushroom-like Au@Pd@Pt tri-metallic nanoparticles. Duan S, Ji YF, Fang PP, et al. Phys. Chem. Chem. Phys. 15(13), 4625-33, (2013)

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Changes in pH and organic acids in mucilage of Eriophorum angustifolium roots after exposure to elevated concentrations of toxic elements. Javed MT, Stoltz E, Lindberg S, et al. Environ. Sci. Pollut. Res. Int. 20(3), 1876-80, (2013)

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Bio-inspired catalytic imine reduction by rhodium complexes with tethered Hantzsch pyridinium groups: evidence for direct hydride transfer from dihydropyridine to metal-activated substrate. McSkimming A, Bhadbhade MM, and Colbran SB Angew. Chem. Int. Ed. Engl. 52(12), 3411-6, (2013)

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Direct and reversible hydrogenation of CO2 to formate by a bacterial carbon dioxide reductase. Schuchmann K and Müller V Science 342(6164), 1382-5, (2013)

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An efficient CoAuPd/C catalyst for hydrogen generation from formic acid at room temperature. Wang ZL, Yan JM, Ping Y, et al. Angew. Chem. Int. Ed. Engl. 52(16), 4406-9, (2013)

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Deletion of Mthfd1l causes embryonic lethality and neural tube and craniofacial defects in mice. Momb J, Lewandowski JP, Bryant JD, et al. Proc. Natl. Acad. Sci. U. S. A. 110(2), 549-54, (2013)

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Immunohistochemical characterization of novel monoclonal antibodies against the N-terminus of amyloid β-peptide. Verwey NA, Hoozemans JJ, Korth C, et al. Amyloid 20(3), 179-87, (2013)

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H2-independent growth of the hydrogenotrophic methanogen Methanococcus maripaludis. Costa KC, Lie TJ, Jacobs MA, et al. MBio 4(2), doi:10.1128/mBio.00062-13, (2013)

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Acid-catalyzed hydrothermal severity on the fractionation of agricultural residues for xylose-rich hydrolyzates. Lee JY, Ryu HJ, and Oh KK Bioresour. Technol. 132, 84-90, (2013)

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Determination of buprenorphine, fentanyl and LSD in whole blood by UPLC-MS-MS. Berg T, Jørgenrud B, and Strand DH J. Anal. Toxicol. 37(3), 159-65, (2013)

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Deoxy-liquefaction of switchgrass in supercritical water with calcium formate as an in-situ hydrogen donor. Ramsurn H and Gupta RB Bioresour. Technol. 143, 575-83, (2013)

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Direct analysis of formate in human plasma, serum and whole blood by in-line coupling of microdialysis to capillary electrophoresis for rapid diagnosis of methanol poisoning. Kubáň P and Boček P Anal. Chim. Acta 768, 82-9, (2013)

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Photocatalytic reduction of nitrate using titanium dioxide for regeneration of ion exchange brine. Yang T, Doudrick K, and Westerhoff P Water Res. 47(3), 1299-307, (2013)

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Capillary electrophoresis with contactless conductometric detection for rapid screening of formate in blood serum after methanol intoxication. Kubáň P, Foret F, and Bocek R J. Chromatogr. A 1281, 142-7, (2013)

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Mechanistic insights into iron catalyzed dehydrogenation of formic acid: β-hydride elimination vs. direct hydride transfer. Yang X Dalton Trans. 42(33), 11987-91, (2013)

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Coordination of FocA and pyruvate formate-lyase synthesis in Escherichia coli demonstrates preferential translocation of formate over other mixed-acid fermentation products. Beyer L, Doberenz C, Falke D, et al. J. Bacteriol. 195(7), 1428-35, (2013)

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Production of hybrid diesel fuel precursors from carbohydrates and petrochemicals using formic acid as a reactive solvent. Zhou X and Rauchfuss TB ChemSusChem 6(2), 383-8, (2013)

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Effects of H2 and formate on growth yield and regulation of methanogenesis in Methanococcus maripaludis. Costa KC, Yoon SH, Pan M, et al. J. Bacteriol. 195(7), 1456-62, (2013)

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Clostridium acidurici electron-bifurcating formate dehydrogenase. Wang S, Huang H, Kahnt J, et al. Appl. Environ. Microbiol. 79(19), 6176-9, (2013)

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Chemical shift powder spectra enhanced by multiple-contact cross-polarization under slow magic-angle spinning. Raya J, Perrone B, and Hirschinger J J. Magn. Reson. 227, 93-102, (2013)

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Four products from Escherichia coli pseudogenes increase hydrogen production. Mohd Yusoff MZ, Hashiguchi Y, Maeda T, et al. Biochem. Biophys. Res. Commun. 439(4), 576-9, (2013)

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Bionanowhiskers from jute: preparation and characterization. Kasyapi N, Chaudhary V, and Bhowmick AK Carbohydr. Polym. 92(2), 1116-23, (2013)

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VhuD facilitates electron flow from H2 or formate to heterodisulfide reductase in Methanococcus maripaludis. Costa KC, Lie TJ, Xia Q, et al. J. Bacteriol. 195(22), 5160-5, (2013)

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Improvement of ethanol productivity and energy efficiency by degradation of inhibitors using recombinant Zymomonas mobilis (pHW20a-fdh). Dong HW, Fan LQ, Luo Z, et al. Biotechnol. Bioeng. 110(9), 2395-404, (2013)

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Optimal design and experimental validation of a simulated moving bed chromatography for continuous recovery of formic acid in a model mixture of three organic acids from Actinobacillus bacteria fermentation. Park C, Nam HG, Lee KB, et al. J. Chromatogr. A 1365, 106-14, (2014)

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Effects of dietary supplementation with two potassium formate sources on performance of 8- to 22-kg pigs. Htoo JK and Molares J J. Anim. Sci. 90 Suppl 4, 346-9, (2012)

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New sulfate-reducing bacteria isolated from Buryatian alkaline brackish lakes: description of Desulfonatronum buryatense sp. nov. Ryzhmanova Y, Nepomnyashchaya Y, Abashina T, et al. Extremophiles 17(5), 851-9, (2013)

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Use of multi-parameter flow cytometry as tool to monitor the impact of formic acid on Saccharomyces carlsbergensis batch ethanol fermentations. Freitas C, Neves E, Reis A, et al. Appl. Biochem. Biotechnol. 169(7), 2038-48, (2013)

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High-level secretory expression of metchnikowin in Escherichia coli. Wu D, Lu Y, Huang H, et al. Protein Expr. Purif. 91(1), 49-53, (2013)

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Effect of acidic condition on the metabolic regulation of Escherichia coli and its phoB mutant. Marzan LW, Hasan CM, and Shimizu K Arch. Microbiol. 195(3), 161-71, (2013)

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Microbiology. An enzymatic route to H2 storage. Pereira IA Science 342(6164), 1329-30, (2013)

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Merck 14,523

Beil. 2,IV,18

Fieser 1,38

Aldrich MSDS 1, 119:D / Corp MSDS 1 (1), 236:B / FT-IR 1 (1), 545:C / FT-IR 2 (1), 848:C / IR-Spectra (3), 324:C / RegBook 1 (1), 601:F / Sax 6, 262 / Sigma FT-IR 1 (2), 1024:A / Structure Index 1, 86:C:2

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