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80910 Fluka

Pivaloyl chloride

purum, ≥98.0% (GC)

Synonym: Trimethylacetyl chloride

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Properties

Related Categories Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks More...
vapor density   >1 (vs air)
vapor pressure   36 mmHg ( 20 °C)
grade   purum
assay   ≥98.0% (GC)
refractive index   n20/D 1.412(lit.)
  n20/D 1.412
bp   105-106 °C(lit.)
density   0.980 g/mL at 20 °C
  0.979 g/mL at 25 °C(lit.)

Price and Availability

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Reacts violently with water.
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
16-26-36/37/39-45
RIDADR 
UN 2438 3(8)(6.1) / PGI
WGK Germany 
1
Flash Point(F) 
66.2 °F
Flash Point(C) 
19 °C

Protocols & Articles

Peer-Reviewed Papers

References

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4'-pivaloyl substituted thymidine as a precursor for the thymyl radical: an EPR spectroscopic study. Schiemann O, Feresin E, Carl T, et al. ChemPhysChem 5(2), 270-4, (2004)

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A facile method for preparation of t-butyloxycarbonylamino acid p-nitroanilides. Noda K, Oda M, Sato M, et al. Int. J. Pept. Protein Res. 36(2), 197-200, (1990)

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Selective pivaloylation of 2-acetamido-2-deoxy sugars. Ljevaković D, Tomić S, and Tomasić J Carbohydr. Res. 182(2), 197-205, (1988)

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Side reactions in the H-phosphonate approach to oligonucleotide synthesis: a kinetic investigation on bisacylphosphite formation and 5'-O-acylation. Sigurdsson S and Strömberg R Nucleosides Nucleotides Nucleic Acids 22(1), 1-12, (2003)

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Synthesis, intramolecular migrations and enzymic hydrolysis of partially pivaloylated methyl alpha-D-mannopyranosides. Tomić S, Petrović V, and Matanović M Carbohydr. Res. 338(6), 491-4, (2003)

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Selective pivaloylation and diphenylacetylation of cyclomalto-oligosaccharides. Santoyo-González F, Isac-García J, Vargas-Berenguel A, et al. Carbohydr. Res. 262(2), 271-82, (1994)

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Stereochemistry of internucleotide bond formation by the H-phosphonate method. 5. The role of Brønsted and H-bonding base catalysis in ribonucleoside H-phosphonate condensation-chemical and stereochemical consequences. Sobkowski M, Stawinski J, and Kraszewski A Nucleosides Nucleotides Nucleic Acids 29(8), 628-45, (2010)

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Beil. 2,IV,912

Fieser 1,1229 / Fieser 8,404

Aldrich MSDS 1, 1784:B / Corp MSDS 1 (2), 3479:C / FT-IR 2 (1), 1224:D / FT-IR 1 (1), 727:B / FT-NMR 1 (1), 1189:B / IR-Spectra (2), 377:G / IR-Spectra (3), 425:H / RegBook 1 (1), 849:D / Sax 6, 1195 / Sigma FT-IR 1 (2), 955:C / Structure Index 1, 131:A:4 / Vapor Phase 3, 769:D

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