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Chloro(dimethyl)thexylsilane

purum, ≥97.0% (GC)

Synonym: Chlorodimethyl(1,1,2-trimethylpropyl)silane, Dimethyl-(2,3-dimethyl-2-butyl)chlorosilane, Dimethyl-thexylchlorosilane, Dimethylthexylsilyl chloride, TDSCl, Thexyldimethylsilyl chloride

  • CAS Number 67373-56-2

  • Linear Formula (CH3)2CHC(CH3)2Si(CH3)2Cl

  • Molecular Weight 178.77

  •  Beilstein Registry Number 3647960

  •  MDL number MFCD00012175

  •  PubChem Substance ID 24889084

  • Popular Documents:  FTNMR (PDF)  

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Properties

Related Categories Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents More...
grade   purum
assay   ≥97.0% (GC)
refractive index   n20/D 1.449(lit.)
  n20/D 1.450
bp   55-56 °C/10 mmHg(lit.)
density   0.909 g/mL at 25 °C(lit.)

Description

Other Notes

Protecting group reagent with some advantages compared to tert-butyldimethylchlorosilane (less expensive, liquid, slightly more stable)1,2,3

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
C
Risk Statements (Europe) 
Safety Statements (Europe) 
26-36/37/39-45
RIDADR 
UN 2986 3(8) / PGII
WGK Germany 
3
Flash Point(F) 
114.8 °F
Flash Point(C) 
46 °C

Protocols & Articles

Peer-Reviewed Papers

References

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1. H.-J. Wetter, K. Oertle Tetrahedron Lett. 26, 5515, (1985)

2. R.D. Walkup, R.T. Cunningham Tetrahedron Lett. 28, 4019, (1987)

3. J. Heberle, G. Simchen, G. van Look Silylating Agents, 2nd ed. Buchs , (1995)

Fieser 13,74

Corp MSDS 1 (1), 1422:A / FT-IR 2 (3), 4353:B / FT-NMR 1 (3), 645:A / RegBook 1 (2), 2959:I / Structure Index 1, 468:D:5 / Vapor Phase 3, 1632:D

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