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8.00834 EMD Millipore

Acrylonitrile

Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis. CAS No. 107-13-1, EC Number 203-466-5., (stabilised with hydroquinone monomethyl ether) for synthesis

Synonym: Acrylic acid nitrile, Vinyl cyanide

  • CAS Number 107-13-1

  • Linear Formula C₃H₃N

  • Molecular Weight 53.06 g/mol

  •  EC Number 203-466-5

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Properties

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packaging   100 ml in Alu bottle (8008340100)
bp   77.3 °C (1013 hPa)
expl. lim.     2.8 - 28 %(V)
vapor pressure   124 hPa (20 °C)
solubility   73 g/l
density   0.81 g/cm3 (20 °C)
flash point   -4.4 °C
autoignition temp.   480 °C
mp   -83.55 °C
pH   6.0 - 7.5 (50 g/l, H₂O, 20 °C)
LD 50 oral   LD50 Rat 78 mg/kg
shipped in   ambient
storage temp.   Store at +2°C to +8°C.
specifications   Assay (GC, area%): ≥ 99 %
  Density (d 20 °C/ 4 °C): 0.805 - 0.807
  Water (K. F.): ≤ 1.0 %
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2926 10 00
Hazard Statement(s) 
H350: May cause cancer.
H225: Highly flammable liquid and vapour.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P201: Obtain special instructions before use.
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P240: Ground/bond container and receiving equipment.
P273: Avoid release to the environment.
P280: Wear protective gloves.
P280: Wear eye protection.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
RTECS 
AT5250000
Storage class 
3 Flammable liquids
WGK 
WGK 3 highly water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1093 , 3 (6.1), I
Declaration (transport by air) IATA-DGR 
UN 1093 , 3 (6.1), I
Declaration (transport by sea) IMDG-Code 
UN 1093 , 3 (6.1), I
Categories of danger 
carcinogenic, toxic, highly flammable, irritant, sensitizing, dangerous for the environment
R Phrase 
R 45-23/24/25-11-37/38-41-43-51/53
May cause cancer.Also toxic by inhalation, in contact with skin and if swallowed.Highly flammable.Irritating to respiratory system and skin.Risk of serious damage to eyes.May cause sensitisation by skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 9-16-53-45-61
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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