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8.00841 EMD Millipore

Methyl acrylate

Methyl acrylate (stabilised with hydroquinone monomethyl ether) for synthesis. CAS 96-33-3, EC Number 202-500-6, chemical formula CH₂=CHCOOCH₃., (stabilised with hydroquinone monomethyl ether) for synthesis

Synonym: Methyl propenoate, Acrylic acid methyl ester

  • CAS Number 96-33-3

  • Linear Formula C₄H₆O₂

  • Molecular Weight 86.09 g/mol

  •  EC Number 202-500-6

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Properties

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packaging   100 ml in Glass bottle (8008410100)
bp   80.1 °C (1013 hPa)
expl. lim.     2.8 %(V)
vapor pressure   93 hPa (20 °C)
solubility   60 g/l
density   0.96 g/cm3 (20 °C)
flash point   -2.7 °C
autoignition temp.   415 °C
viscosity kinematic   10 mm2/s (23 °C)
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99,0 Area %
  Density (d 20 °C/ 4 °C): 0,954 - 0,958
  Identity (IR): conforms

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Safety Information

HS Code 
2916 12 00
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H302 + H312: Harmful if swallowed or in contact with skin
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s) 
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground/bond container and receiving equipment.
P273: Avoid release to the environment.
P280: Wear protective gloves.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
RTECS 
at2800000
Storage class 
3 Flammable liquids
WGK 
WGK 2 water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Harmful  Harmful
Declaration (railroad and road) ADR, RID 
UN 1919 , 3, II
Declaration (transport by air) IATA-DGR 
UN 1919 , 3, II
Declaration (transport by sea) IMDG-Code 
UN 1919 , 3, II
Categories of danger 
highly flammable, harmful, irritant, sensitizing
R Phrase 
R 11-20/21/22-36/37/38-43
Highly flammable.Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.May cause sensitisation by skin contact.
S Phrase 
S 9-25-26-33-36/37-43
Keep container in a well-ventilated place.Avoid contact with eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing and gloves.In case of fire, use fire-fighting equipment on basis class D.
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