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8.01021 EMD Millipore

3-Bromo-1-propene

3-Bromo-1-propene (stabilised) for synthesis. CAS No. 106-95-6, EC Number 203-446-6., (stabilised) for synthesis

Synonym: Allyl bromide

  • CAS Number 106-95-6

  • Linear Formula C₃H₅Br

  • Molecular Weight 120.98 g/mol

  •  EC Number 203-446-6

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Properties

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packaging   1 l in Glass bottle (8010211000)
  250 ml in Glass bottle (8010210250)
bp   70 - 72 °C (1013 mbar)
expl. lim.     4.3 - 7.3 %(V)
density   1.428 - 1.432 g/cm3 (20 °C)
flash point   -1 °C
autoignition temp.   295 °C
mp   -119 °C
LD 50 oral   LD50 Rat 120 mg/kg
shipped in   ambient
storage temp.   Store at +2°C to +8°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Density (d 20 °C/ 4 °C): 1.428 - 1.432
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2903 39 19
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H301 + H331: Toxic if swallowed or if inhaled
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.
Precautionary Statement(s) 
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P240: Ground/bond container and receiving equipment.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
RTECS 
UC7090000
Storage class 
3 Flammable liquids
WGK 
WGK 2 water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1099 , 3 (6.1), I
Declaration (transport by air) IATA-DGR 
UN 1099 , 3 (6.1), I
Declaration (transport by sea) IMDG-Code 
UN 1099 , 3 (6.1), I, Marine Pollutant: P, Segregation Group: 10 (Liquid halogenated hydrocarbons)
Categories of danger 
highly flammable, toxic, corrosive, dangerous for the environment
R Phrase 
R 11-23/25-34-50
Highly flammable.Toxic by inhalation and if swallowed.Causes burns.Very toxic to aquatic organisms.
S Phrase 
S 16-26-36/37/39-45-61
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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