8.01809 EMD Millipore

Benzyl chloride

Benzyl chloride for synthesis. CAS No. 100-44-7, EC Number 202-853-6., for synthesis

  • CAS Number 100-44-7

  • Linear Formula C₇H₇Cl

  • Molecular Weight 126.58 g/mol

  •  EC Number 202-853-6



Related Categories Biochemicals and Reagents More...
packaging   100 ml in Glass bottle (8018090100)
  50 kg in Barrel PE/met (8018099050)
bp   179.3 °C (1013 hPa)
expl. lim.     1.1 - 14 %(V)
vapor pressure   1.2 hPa (20 °C)
solubility   460 mg/l
density   1.10 g/cm3 (20 °C)
flash point   67 °C
autoignition temp.   585 °C
mp   -39 °C
LD 50 oral   LD50 Rat 440 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Density (d 20 °C/ 4 °C): 1.099 - 1.100
  Identity (IR): passes test

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Safety Information

HS Code 
2903 99 80
Hazard Statement(s) 
H350: May cause cancer.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H331: Toxic if inhaled.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary Statement(s) 
P201: Obtain special instructions before use.
P280: Wear protective gloves.
P280: Wear eye protection.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 3 highly water endangering
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1738 , 6.1 (8), II
Declaration (transport by air) IATA-DGR 
UN 1738 , 6.1 (8), II
Declaration (transport by sea) IMDG-Code 
UN 1738 , 6.1 (8), II, Segregation Group: 1 (Acids)10 (Liquid halogenated hydrocarbons)
Categories of danger 
carcinogenic, toxic, irritant
R Phrase 
R 45-22-23-48/22-37/38-41
May cause cancer.Also harmful if swallowed.Also toxic by inhalation.Also harmful: danger of serious damage to health by prolonged exposure if swallowed.Irritating to respiratory system and skin.Risk of serious damage to eyes.
S Phrase 
S 53-45
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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