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8.01816 EMD Millipore

Benzyltrimethylammonium hydroxide

(40% solution in methanol) for synthesis

Synonym: Trimethylbenzylammonium hydroxide, Triton B

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Properties

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packaging   100 ml in Glass bottle (8018160100)
bp   65 °C (1013 hPa)
expl. lim.     5.1 - 44 %(V)
vapor pressure   127 hPa (20 °C)
density   0.93 g/cm3 (20 °C)
flash point   15 °C
autoignition temp.   455 °C
mp   -98 °C
pH   12 (H₂O, 20 °C) (undiluted)
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (acidimetric): 39.0 - 43.0 %
  Water (K. F.): ≤ 3.0 %
  Colour number (Apha): ≤ 200
  Identity (IR): passes test

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Safety Information

HS Code 
3824 99 92
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H314: Causes severe skin burns and eye damage.
H370: Causes damage to organs.
Precautionary Statement(s) 
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P235: Store in a well-ventilated place. Keep cool.
Storage class 
3 Flammable Liquids
WGK 
WGK 2 water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 2924 , 3 (6.1, 8), II
Declaration (transport by air) IATA-DGR 
UN 2924 , 3 (6.1, 8), II
Declaration (transport by sea) IMDG-Code 
UN 2924 , 3 (6.1, 8), II, Segregation Group: 18 (Alkalis)
Categories of danger 
highly flammable, toxic, corrosive
R Phrase 
R 11-23/24/25-35-39/23/24/25
Highly flammable.Toxic by inhalation, in contact with skin and if swallowed.Causes severe burns.Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
S Phrase 
S 16-26-36/37/39-45
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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