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8.02295 EMD Millipore

4-Chloro-3-methylphenol

4-Chloro-3-methylphenol for synthesis. CAS 59-50-7, chemical formula 4-(Cl)-3-(CH₃)C₆H₃OH., for synthesis

Synonym: 4-Chloro-m-cresol, 2-Chloro-5-hydroxytoluene

  • CAS Number 59-50-7

  • Linear Formula C₇H₇ClO

  • Molecular Weight 142.58 g/mol

  •  EC Number 200-431-6

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Properties

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packaging   5 g in Glass bottle (8022950005)
bp   235 - 239 °C (1013 hPa)
vapor pressure   <0.1 hPa (20 °C)
solubility   3.9 g/l
density   1.37 g/cm3 (20 °C)
flash point   118 °C
autoignition temp.   590 °C
mp   63 - 65 °C
pH   6.5 (1 g/l, H₂O, 20 °C)
bulk density   800 kg/m3
LD 50 oral   LD50 Rat 1830 mg/kg
LD 50 dermal   LD50 Rat > 2000 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Melting range (lower value): ≥ 64 °C
  Melting range (upper value): ≤ 67 °C
  Identity (IR): passes test

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Safety Information

HS Code 
2908 19 00
Hazard Statement(s) 
H312: Harmful in contact with skin.
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H317: May cause an allergic skin reaction.
H400: Very toxic to aquatic life.
Precautionary Statement(s) 
P280: Wear protective gloves/ eye protection/ face protection.
P273: Avoid release to the environment.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P313: Get medical advice/ attention.
RTECS 
GO7100000
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 
WGK 2 water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Harmful  Harmful
Declaration (railroad and road) ADR, RID 
UN 3437 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 3437 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 3437 , 6.1, II
Categories of danger 
harmful, irritant, sensitizing, dangerous for the environment
R Phrase 
R 21/22-41-43-50
Harmful in contact with skin and if swallowed.Risk of serious damage to eyes.May cause sensitisation by skin contact.Very toxic to aquatic organisms.
S Phrase 
S 26-36/37/39-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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