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8.06209 EMD Millipore

3-Nitroaniline

3-Nitroaniline for synthesis. CAS No. 99-09-2, EC Number 202-729-1., for synthesis

Synonym: m-Nitraniline

  • CAS Number 99-09-2

  • Linear Formula C₆H₆N₂O₂

  • Molecular Weight 138.13 g/mol

  •  EC Number 202-729-1

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Properties

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packaging   5 g in Glass bottle (8062090005)
bp   306 °C (1013 hPa) decomposes
vapor pressure   1 hPa (104 °C)
solubility   1.25 g/l
density   0.9 g/cm3 (25 °C)
flash point   196 °C
autoignition temp.   521 °C
mp   109 - 112 °C
LD 50 oral   LD50 Rat 535 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (HPLC, area%): ≥ 99.0 % (a/a)
  Melting range (lower value): ≥ 109 °C
  Melting range (upper value): ≤ 112 °C
  Identity (IR): passes test

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Safety Information

HS Code 
2921 42 00
Hazard Statement(s) 
H331: Toxic if inhaled.
H311: Toxic in contact with skin.
H301: Toxic if swallowed.
H373: May cause damage to organs through prolonged or repeated exposure.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 
WGK 3 highly water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1661 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 1661 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 1661 , 6.1, II
Categories of danger 
toxic, dangerous for the environment
R Phrase 
R 23/24/25-33-52/53
Toxic by inhalation, in contact with skin and if swallowed.Danger of cumulative effects.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 28-36/37-45-61
After contact with skin, wash immediately with plenty of soap and water.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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