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8.06232 EMD Millipore

1-Chloro-2-nitrobenzene

1-Chloro-2-nitrobenzene for synthesis. CAS 88-73-3, pH 6 (0.4 g/l, H₂O, 20 °C)., for synthesis

Synonym: 1-Nitro-2-chlorine benzene

  • CAS Number 88-73-3

  • Linear Formula C₆H₄ClNO₂

  • Molecular Weight 157.55 g/mol

  •  EC Number 201-854-9

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Properties

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bp   243 °C (1013 hPa)
expl. lim.     1.15 - 13.1 %(V)
vapor pressure   0.43 hPa (50 °C)
solubility   0.59 g/l
density   1.37 g/cm3 (20 °C)
flash point   128 °C
autoignition temp.   470 °C
mp   31 - 33 °C
pH   6 (0.4 g/l, H₂O, 20 °C)
LD 50 oral   LD50 Rat 251 mg/kg
LD 50 dermal   LD50 Rabbit 450 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Melting range (lower value): ≥ 31 °C
  Melting range (upper value): ≤ 33 °C
  Identity (IR): passes test
  Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

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Safety & Documentation

Safety Information

HS Code 
2904 99 00
Hazard Statement(s) 
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H351: Suspected of causing cancer.
H361f: Suspected of damaging fertility.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 
WGK 2 water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1578 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 1578 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 1578 , 6.1, II
Categories of danger 
toxic, carcinogenic, dangerous for the environment, toxic for reproduction
R Phrase 
R 23/24/25-40-51/53-62
Toxic by inhalation, in contact with skin and if swallowed.Limited evidence of a carcinogenic effect.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Possible risk of impaired fertility.
S Phrase 
S 28-36/37-45-61
After contact with skin, wash immediately with plenty of soap and water, if possible also with polyethylene glycol 400.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.

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