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8.06749 EMD Millipore

Nickel-aluminium alloy

(powder) for the production of Raney nickel for synthesis

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Properties

Related Categories Materials Science, Metal and Ceramic Science, Metals More...
packaging   250 g in Plastic bottle (8067490250)
  5 g in Glass bottle (8067490005)
density   4.3 g/cm3
mp   1460 °C
bulk density   2850 kg/m3
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay of Ni: 47.0 - 53.0 %
  Assay of Al: 47.0 - 53.0 %

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Safety & Documentation

Safety Information

HS Code 
7502 20 00
Hazard Statement(s) 
H261: In contact with water releases flammable gases.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H372: Causes damage to organs through prolonged or repeated exposure.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P280: Wear protective gloves.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P402 + P404: Store in a dry place. Store in a closed container.
Storage class 
4.3 Hazardous materials, which set free flammable gases upon contact with water
WGK 
WGK 3 highly water endangering
Disposal 
26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1396 , 4.3, III
Declaration (transport by air) IATA-DGR 
UN 1396 , 4.3, III
Declaration (transport by sea) IMDG-Code 
UN 1396 , 4.3, III, Segregation Group: 15 (Powdered metals)
Categories of danger 
highly flammable, carcinogenic, sensitizing, toxic, dangerous for the environment
R Phrase 
R 15-40-43-48/23-52/53
Contact with water liberates extremely flammable gases.Limited evidence of a carcinogenic effect.May cause sensitisation by skin contact.Toxic: danger of serious damage to health by prolonged exposure through inhalation.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 8-22-36/37-43-45-61
Keep container dry.Do not breathe dust.Wear suitable protective clothing and gloves.In case of fire, use metal-fire powder. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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