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8.07047 EMD Millipore

(S)-(-)-1-Phenylethylamine

(S)-(-)-1-Phenylethylamine for the resolution of racemates for synthesis. CAS 2627-86-3, chemical formula C₆H₅CH(CH₃)NH₂., for the resolution of racemates for synthesis

Synonym: L-α-Methylbenzylamine

  • CAS Number 2627-86-3

  • Linear Formula C₈H₁₁N

  • Molecular Weight 121.18 g/mol

  •  EC Number 220-098-0

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Properties

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packaging   10 ml in Glass bottle (8070470010)
bp   187 °C (1013 hPa)
vapor pressure   0.4 hPa (20 °C)
solubility   42 g/l
density   0.95 g/cm3 (20 °C)
flash point   71 °C
autoignition temp.   355 °C
mp   -10 °C
pH   >7 (H₂O, 20 °C) (undiluted)
LD 50 oral   LD50 Rat 980 mg/kg
LD 50 dermal   LD50 Rabbit 730 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Density (d 20 °C/ 4 °C): 0.951 - 0.953
  Spec. rotation [α²0/D (undiluted): -40.0 - -38.0 °
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2921 49 00
Hazard Statement(s) 
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s) 
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK 
WGK 1 slightly water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Symbols 
Corrosive  Corrosive
Declaration (railroad and road) ADR, RID 
UN 2922 , 8 (6.1), II
Declaration (transport by air) IATA-DGR 
UN 2922 , 8 (6.1), II
Declaration (transport by sea) IMDG-Code 
UN 2922 , 8 (6.1), II, Segregation Group: 18 (Alkalis)
Categories of danger 
harmful, corrosive
R Phrase 
R 21/22-34
Harmful in contact with skin and if swallowed.Causes burns.
S Phrase 
S 26-28-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of water.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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