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8.07250 EMD Millipore

Phenylhydrazine

Phenylhydrazine for synthesis. CAS 100-63-0, EC Number 202-873-5, chemical formula C₆H₅NHNH₂., for synthesis

  • CAS Number 100-63-0

  • Linear Formula C₆H₈N₂

  • Molecular Weight 108.14 g/mol

  •  EC Number 202-873-5

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Properties

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bp   244 °C (1013 hPa)
expl. lim.     1.1 %(V)
vapor pressure   0.1 hPa (20 °C)
solubility   145 g/l
density   1.10 g/cm3 (20 °C)
flash point   88 °C
autoignition temp.   195 °C
mp   19.6 °C
LD 50 oral   LD50 Rat 188 mg/kg
storage temp.   Store below +30°C.
specifications   Assay (HClO₄): ≥ 97.0 %
  Density (d 20 °C/ 4 °C): 1.096 - 1.099
  Identity (IR): passes test
  Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

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Safety Information

HS Code 
2928 00 90
Hazard Statement(s) 
H350: May cause cancer.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H341: Suspected of causing genetic defects.
H372: Causes damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
Precautionary Statement(s) 
P201: Obtain special instructions before use.
P273: Avoid release to the environment.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
RTECS 
MV8925000
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 
WGK 3 highly water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 2572 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 2572 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 2572 , 6.1, II
Categories of danger 
carcinogenic, toxic, irritant, sensitizing, dangerous for the environment, mutagenic
R Phrase 
R 45-23/24/25-48/23/24/25-36/38-68-43-50
May cause cancer.Also toxic by inhalation, in contact with skin and if swallowed.Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.Possible risk of irreversible effects.May cause sensitisation by skin contact.Very toxic to aquatic organisms.
S Phrase 
S 53-36/37-45-61
Avoid exposure - obtain special instructions before use.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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