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8.07494 EMD Millipore

Pyrrolidine

Pyrrolidine for synthesis. CAS 123-75-1, pH 12.9 (100 g/l, H₂O, 20 °C)., for synthesis

Synonym: Tetramethyleneimine

  • CAS Number 123-75-1

  • Linear Formula C₄H₉N

  • Molecular Weight 71.12 g/mol

  •  EC Number 204-648-7

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Properties

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packaging   250 ml in Glass bottle (8074940250)
  5 ml in Glass bottle (8074940005)
bp   86 - 88 °C (1013 hPa)
expl. lim.     1.6 - 10.6 %(V)
vapor pressure   65 hPa (20 °C)
density   0.86 g/cm3 (20 °C)
flash point   3 °C
autoignition temp.   345 °C
mp   -63 °C
pH   12.9 (100 g/l, H₂O, 20 °C)
LD 50 oral   LD50 Rat 433 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Density (d 20 °C/ 4 °C): 0.859 - 0.861
  Water (K. F.): ≤ 0.50 %
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2933 99 80
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H332: Harmful if inhaled.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
Precautionary Statement(s) 
P210: Keep away from heat.
P233: Keep container tightly closed.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
RTECS 
UX9650000
Storage class 
3 Flammable liquids
WGK 
WGK 1 slightly water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Symbols 
Corrosive  Corrosive
Hazard Symbols 
Flammable  Flammable
Declaration (railroad and road) ADR, RID 
UN 1922 , 3 (8), II
Declaration (transport by air) IATA-DGR 
UN 1922 , 3 (8), II
Declaration (transport by sea) IMDG-Code 
UN 1922 , 3 (8), II, Segregation Group: 18 (Alkalis)
Categories of danger 
highly flammable, harmful, corrosive
R Phrase 
R 11-20/22-35
Highly flammable.Harmful by inhalation and if swallowed.Causes severe burns.
S Phrase 
S 16-26-28-36/37/39-45
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of water.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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