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8.08265 EMD Millipore

Tris(triphenylphosphine)rhodium(I) chloride (11% Rh)

Tris(triphenylphosphine)rhodium(I) chloride (11% Rh) for synthesis. CAS 14694-95-2, EC 238-744-5, chemical formula (C₆H₅)₃P₃RhCl., for synthesis

Synonym: Chlorotris(triphenylphosphine)rhodium(I), Wilkinsoncatalyst

  • CAS Number 14694-95-2

  • Linear Formula C₅₄H₄₅ClP₃Rh

  • Molecular Weight 925.23 g/mol

  •  EC Number 238-744-5



packaging   1 g in Glass bottle (8082650001)
mp   157 °C
LD 50 oral   LD50 Rat > 5110 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (to C, H): ≥ 97.0 %

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Safety Information

HS Code 
2843 90 90
Hazard Statement(s) 
H317: May cause an allergic skin reaction.
H413: May cause long lasting harmful effects to aquatic life.
Precautionary Statement(s) 
P260: Do not breathe dust.
P273: Avoid release to the environment.
P280: Wear protective gloves.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
Storage class 
8A Combustible, corrosive hazardous materials
WGK 1 slightly water endangering
Residues containing valuable recoverable metals should be forwarded for recycling. Container H.
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Irritant  Irritant
Declaration (railroad and road) ADR, RID 
Kein Gefahrgut
Declaration (transport by air) IATA-DGR 
No Dangerous Good
Declaration (transport by sea) IMDG-Code 
No Dangerous Good
R Phrase 
R 43-53
May cause sensitisation by skin contact.May cause long-term adverse effects in the aquatic environment.
S Phrase 
S 36/37-61-22
Wear suitable protective clothing and gloves.Avoid release to the environment. Refer to special instructions/ Safety data sheets.Do not breathe dust.
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