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8.08315 EMD Millipore

p-Toluidine

p-Toluidine for synthesis. CAS 106-49-0, EC Number 203-403-1, chemical formula CH₃C₆H₄NH₂., for synthesis

Synonym: 4-Aminotoluene, 4-Methylaniline

  • CAS Number 106-49-0

  • Linear Formula C₇H₉N

  • Molecular Weight 107.15 g/mol

  •  EC Number 203-403-1

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Properties

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packaging   5 g in Glass bottle (8083150005)
vapor pressure   1.3 hPa (50 °C)
solubility   7.5 g/l
density   1.05 g/cm3 (20 °C)
flash point   87 °C
autoignition temp.   480 °C
mp   43 °C
LD 50 oral   LD50 Rat 336 mg/kg
LD 50 dermal   LD50 Rabbit 890 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 99.0 % (a/a)
  Melting range (lower value): ≥ 43 °C
  Melting range (upper value): ≤ 46 °C
  Identity (IR): passes test
  Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

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Safety & Documentation

Safety Information

HS Code 
2921 43 00
Hazard Statement(s) 
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H351: Suspected of causing cancer.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
RTECS 
XU3150000
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 
WGK 2 water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 3451 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 3451 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 3451 , 6.1, II, Marine Pollutant: P
Categories of danger 
toxic, irritant, carcinogenic, sensitizing, dangerous for the environment
R Phrase 
R 23/24/25-36-40-43-50
Toxic by inhalation, in contact with skin and if swallowed.Irritating to eyes.Limited evidence of a carcinogenic effect.May cause sensitisation by skin contact.Very toxic to aquatic organisms.
S Phrase 
S 28-36/37-45-61
After contact with skin, wash immediately with plenty of soap and water.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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