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8.14519 EMD Millipore

Lithium methylate

(10% solution in methanol) for synthesis

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Properties

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packaging   100 ml in Glass bottle (8145190100)
expl. lim.     5.5 - 36.5 %(V) Methanol
vapor pressure   128 hPa (20 °C)
density   0.86 g/cm3 (20 °C)
flash point   9 °C
autoignition temp.   455 °C Methanol
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (acidimetric): 9.0 - 11.0 %
  Density (d 20 °C/ 4 °C): 0.853 - 0.859

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Safety & Documentation

Safety Information

HS Code 
3824 99 92
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H314: Causes severe skin burns and eye damage.
H370: Causes damage to organs.
EUH014: Reacts violently with water.
Precautionary Statement(s) 
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground/bond container and receiving equipment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Storage class 
3 Flammable liquids
WGK 
WGK 1 slightly water endangering
Disposal 
13
Bases and alcoholates should be diluted if necessary by carefully stirring them into water and then neutralized (protective gloves, fume cupboard!) with hydrochloric acid (Cat. No. 100312). Before placing in container D, check the pH with pH universal indicator strips (Cat. No. 109535).
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 3274 , 3 (8), II
Declaration (transport by air) IATA-DGR 
UN 3274 , 3 (8), II
Declaration (transport by sea) IMDG-Code 
UN 3274 , 3 (8), II, Segregation Group: 18 (Alkalis)
Categories of danger 
highly flammable, toxic, corrosive
R Phrase 
R 11-14-23/24/25-34-39/23/24/25
Highly flammable.Reacts violently with water.Toxic by inhalation, in contact with skin and if swallowed.Causes burns.Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
S Phrase 
S 8-16-26-36/37/39-45
Keep container dry.Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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