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8.14566 EMD Millipore

Diisopropylazodicarboxylate

Diisopropylazodicarboxylate for synthesis. CAS 2446-83-5, chemical formula (CH₃)₂CHO₂CN=NCO₂CH(CH₃)₂., for synthesis

  • CAS Number 2446-83-5

  • Linear Formula C₈H₁₄N₂O₄

  • Molecular Weight 202.2 g/mol

  •  EC Number 219-502-8

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Properties

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bp   75 °C (33.3 Pa)
vapor pressure   1.04 hPa (20 °C)
density   1.03 g/cm3 (20 °C)
flash point   106 °C
LD 50 dermal   LD50 Rabbit 2150 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 95.0 % (a/a)
  Density (d 20 °C/ 4 °C): 1.038 - 1.048
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2927 00 00
Hazard Statement(s) 
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage class 
10 - 13 Other liquids and solids
WGK 
WGK 2 water endangering
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Irritant  Irritant
Declaration (railroad and road) ADR, RID 
UN 3082 , 9, III
Declaration (transport by air) IATA-DGR 
UN 3082 , 9, III
Declaration (transport by sea) IMDG-Code 
UN 3082 , 9, III, Marine Pollutant: P
Categories of danger 
irritant, dangerous for the environment
R Phrase 
R 36/37/38-51/53
Irritating to eyes, respiratory system and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 26-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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