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8.14974 EMD Millipore

Phenyllithium

(20% solution in dibutylether) for synthesis

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Properties

packaging   100 ml in Glass bottle (8149740100)
density   0.85 g/cm3
flash point   25 °C Information refers to the main component.
shipped in   ambient
storage temp.   Store at +2°C to +8°C.
specifications   Assay (total alcalinity): 18.0 - 22.0 %

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Safety & Documentation

Safety Information

HS Code 
2931 90 00
Hazard Statement(s) 
H226: Flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.
EUH014: Reacts violently with water.
Precautionary Statement(s) 
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
3 Flammable Liquids
WGK 
WGK 3 highly water endangering
Disposal 
8
Hydrolysis-sensitive organoelement compounds and metal alkyls, which are as a rule dissolved in organic solvents, should be carefully stirred dropwise into 1-butanol (Cat. No. 822262) in a hood with the front screen closed. Any flammable gases formed should be fed via a tube directly into the extractor duct. When gas development has ceased, continue stirring for one hour and add an excess of water. Container A.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Symbols 
Corrosive  Corrosive
Declaration (railroad and road) ADR, RID 
UN 2920 , 8 (3), II
Declaration (transport by air) IATA-DGR 
UN 2920 , 8 (3), II
Declaration (transport by sea) IMDG-Code 
UN 2920 , 8 (3), II
Categories of danger 
flammable, corrosive, dangerous for the environment
R Phrase 
R 10-14-34-37-52/53
Flammable.Reacts violently with water.Causes burns.Irritating to respiratory system.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 7/9-26-36/37/39-45-61
Keep container tightly closed and in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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