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8.16023 EMD Millipore

Sodium-bis(trimethylsilyl)amide

(2 molare solution in tetrahydrofurane) for synthesis

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Properties

expl. lim.     1.5 - 12.4 %(V) (THF)
density   0.916 g/cm3 (20 °C)
flash point   -20 °C (THF)
autoignition temp.   215 °C (THF)
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (HClO₄): 1.8 - 2.2 mol/l

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Safety & Documentation

Safety Information

HS Code 
3824 99 92
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects.
H351: Suspected of causing cancer.
H412: Harmful to aquatic life with long lasting effects.
EUH019: May form explosive peroxides.
Precautionary Statement(s) 
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground/bond container and receiving equipment.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
Storage class 
3 Flammable liquids
WGK 
WGK 3 highly water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Corrosive  Corrosive
Hazard Symbols 
Flammable  Flammable
Declaration (railroad and road) ADR, RID 
UN 2924 , 3 (8), II
Declaration (transport by air) IATA-DGR 
UN 2924 , 3 (8), II
Declaration (transport by sea) IMDG-Code 
UN 2924 , 3 (8), II
Categories of danger 
highly flammable, corrosive, carcinogenic
R Phrase 
R 11-19-34-37-40-68-52/53
Highly flammable.May form explosive peroxides.Causes burns.Irritating to respiratory system.Limited evidence of a carcinogenic effect.Possible risk of irreversible effects.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 16-26-36/37/39-45-61
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.

Documents

Certificate of Analysis

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