• USA Home
  • 8.18571 - Ethyl 4-chloroacetoacetate

EMAIL THIS PAGE TO A FRIEND
8.18571 EMD Millipore

Ethyl 4-chloroacetoacetate

Ethyl 4-chloroacetoacetate for synthesis. CAS 638-07-3, EC Number 211-317-0, chemical formula ClCH₂COCH₂COOC₂H₅., for synthesis

Synonym: 4-Chloroacetoacetic acid ethyl ester

  • CAS Number 638-07-3

  • Linear Formula C₆H₉ClO₃

  • Molecular Weight 164.59 g/mol

  •  EC Number 211-317-0

Purchase

Properties

Related Categories Biochemicals and Reagents More...
packaging   100 ml in Glass bottle (8185710100)
bp   220 °C (1013 hPa)
expl. lim.     1.8 %(V)
vapor pressure   0.1 hPa (20 °C)
solubility   47.0 g/l
density   1.21 g/cm3 (20 °C)
flash point   106 °C
autoignition temp.   320 °C
mp   -8 °C
pH   2.9 (10 g/l, H₂O, 20 °C)
LD 50 oral   LD50 Rat 180 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 94.0 % (a/a)
  Density (d 20 °C/ 4 °C): 1.208 - 1.210
  Identity (IR): passes test

Price and Availability


Ask us for bulk and customization needs

My Chemicals
Safety & Documentation

Safety Information

HS Code 
2918 30 00
Hazard Statement(s) 
H301 + H311: Toxic if swallowed or in contact with skin
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
RTECS 
AK5110000
Storage class 
6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK 
WGK 3 highly water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 2922 , 8 (6.1), II
Declaration (transport by air) IATA-DGR 
UN 2922 , 8 (6.1), II
Declaration (transport by sea) IMDG-Code 
UN 2922 , 8 (6.1), II
Categories of danger 
toxic, corrosive, sensitizing, dangerous for the environment
R Phrase 
R 24/25-34-43-51/53
Toxic in contact with skin and if swallowed.Causes burns.May cause sensitisation by skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 26-36/37/39-45-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
Protocols & Articles
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?